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Performance of Bifunctional СuO–CeO2/γ-Al2O3 Catalyst in Dimethoxymethane Steam Reforming to Hydrogen-Rich Gas for Fuel Cell Feeding Научная публикация

Журнал Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883
Вых. Данные Год: 2015, Том: 166-167, Страницы: 535-543 Страниц : 9 DOI: 10.1016/j.apcatb.2014.12.008
Ключевые слова Copper-ceria-alumina, Dimethoxymethane, Dimethyl ether, Hydrogen, Methanol
Авторы Pechenkin A.A. 1,2 , Badmaev S.D. 1,2 , Belyaev V.D. 1,2 , Sobyanin V.A. 1
Организации
1 Boreskov Institute of Catalysis, Pr. Lavrentieva, 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova St., 2, Novosibirsk 630090, Russia

Информация о финансировании (3)

1 Российский фонд фундаментальных исследований 14-03-00457
2 Министерство образования и науки Российской Федерации
3 Совет по грантам Президента Российской Федерации МК-2199.2013.3

Реферат: Dimetoxymethane steam reforming (DMM SR) to hydrogen-rich gas over a bifunctional СuO–CeO2/γ-Al2O3 catalyst was studied. The performance of γ-Al2O3, CeO2/γ-Al2O3, and СuO/γ-Al2O3 under DMM SR conditions was studied as well to elucidate the role of each catalyst component. BET, TPR, FTIR spectroscopy, XRD, TEM, EDXA and HAADF-STEM techniques were used for catalyst characterization. Complete DMM conversion was observed over the СuO–CeO2/γ-Al2O3 catalyst under atmospheric pressure, T = 300 °C, GHSV = 10,000 h−1 and H2O/DMM = 5 mol/mol with hydrogen productivity of 15.5 L H2/(gcat·h) and CO content in the hydrogen-rich gas below the equilibrium value. DMM SR proceeds via a consecutive two-step reaction mechanism including DMM hydration to methanol and formaldehyde on γ-Al2O3 acid sites and steam reforming of the formed methanol and formaldehyde to hydrogen-rich gas on alumina-supported mixed copper–cerium oxide species. The СuO–CeO2/γ-Al2O3 catalyst proved to be highly promising for multi-fuel processor approach: steam reforming of DMM, dimethyl ether and methanol on the same catalyst under similar reaction conditions to hydrogen-rich gas for fuel cell feeding.
Библиографическая ссылка: Pechenkin A.A. , Badmaev S.D. , Belyaev V.D. , Sobyanin V.A.
Performance of Bifunctional СuO–CeO2/γ-Al2O3 Catalyst in Dimethoxymethane Steam Reforming to Hydrogen-Rich Gas for Fuel Cell Feeding
Applied Catalysis B: Environmental. 2015. V.166-167. P.535-543. DOI: 10.1016/j.apcatb.2014.12.008 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 15 сент. 2014 г.
Принята к публикации: 3 дек. 2014 г.
Опубликована online: 5 дек. 2014 г.
Опубликована в печати: 1 мая 2015 г.
Идентификаторы БД:
Web of science: WOS:000348753400059
Scopus: 2-s2.0-84919933556
РИНЦ: 23962829
Chemical Abstracts: 2014:2091474
Chemical Abstracts (print): 162:164043
OpenAlex: W2013584664
Цитирование в БД:
БД Цитирований
Web of science 33
Scopus 37
РИНЦ 38
OpenAlex 38
Альметрики: