Abstract: X-ray diffraction (XRD), selected area diffraction (SAD), radial distribution function (RDF) and high resolution transmission electron microscopy (HREM) techniques were used for studying the role of the Ru additives in the stabilization of carbon-supported palladium catalysts at high temperatures in hydrogen atmosphere of (250–650 °C) and under the action of reaction medium (250–285 °C) in process of terephthalic acid (TPA) hydropurification. It is shown that the introduction of ruthenium in the composition of palladium catalysts results in the increase of their sintering stability. A decrease in the dispersity of bimetallic catalysts at high temperatures happens mainly due to the sintering of Pd metal particles; the Ru particles in these conditions maintain a high dispersity and exist as an individual phase.

Cite: Romanenko A.V. , Tyschhishin E.A. , Moroz E.M. , Likholobov V.A. , Zaikovskii V.I. , Jhung S. , Park Y.-S.
Influence of Ruthenium Addition on Sintering of Carbon-Supported Palladium
Applied Catalysis A: General. 2002. V.227. N1-2. P.117-123. DOI: 10.1016/S0926-860X(01)00928-0 WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Submitted:	Jun 21, 2001
Accepted:	Oct 18, 2001
Published online:	Feb 12, 2002
Published print:	Mar 8, 2002

Identifiers:

Web of science:	WOS:000174265400011
Scopus:	2-s2.0-0037040320
Elibrary:	13399388
Chemical Abstracts:	2002:135109
Chemical Abstracts (print):	136:237421
OpenAlex:	W2053062378

Citing:

DB	Citing
Web of science	22
Scopus	25
Elibrary	26
OpenAlex	23

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