Competing Michael and Knoevenagel Reactions of Terpenoids with Malononitrile on Basic Cs-beta Zeolite Full article
| Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2003, Volume: 195, Number: 1-2, Pages: 263-274 Pages count : 12 DOI: 10.1016/S1381-1169(02)00581-2 | ||||
| Tags | Basic zeolite, Knoevenagel reaction, Michael reaction, Tandem reactions, Terpenoids | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 00-03-32721 |
Abstract:
Basic cesium-beta (Cs-beta) zeolite has been synthesized. It proved to be an effective catalyst in reactions of a number of α,β-unsaturated carbonyl compounds with malononitrile. It is shown that the process is either the Michael or Knoevenagel reaction, or tandem transformations generally initiated by the Michael reaction, which depends on steric hindrance at the carbonyl group and the β-position of the carboncarbon (CC) double bond adjacent to the carbonyl group.
Cite:
Volcho K.P.
, Kurbakova S.Y.
, Korchagina D.V.
, Suslov E.V.
, Salakhutdinov N.F.
, Toktarev A.V.
, Echevsky G.V.
, Barkhash V.A.
Competing Michael and Knoevenagel Reactions of Terpenoids with Malononitrile on Basic Cs-beta Zeolite
Journal of Molecular Catalysis A: Chemical. 2003. V.195. N1-2. P.263-274. DOI: 10.1016/S1381-1169(02)00581-2 WOS Scopus РИНЦ ANCAN OpenAlex
Competing Michael and Knoevenagel Reactions of Terpenoids with Malononitrile on Basic Cs-beta Zeolite
Journal of Molecular Catalysis A: Chemical. 2003. V.195. N1-2. P.263-274. DOI: 10.1016/S1381-1169(02)00581-2 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | May 27, 2002 |
| Accepted: | Oct 18, 2002 |
| Published online: | Dec 4, 2002 |
| Published print: | Mar 18, 2003 |
Identifiers:
| Web of science: | WOS:000181647600027 |
| Scopus: | 2-s2.0-0037452935 |
| Elibrary: | 13436717 |
| Chemical Abstracts: | 2003:162153 |
| Chemical Abstracts (print): | 139:53161 |
| OpenAlex: | W2077870549 |