Catalysts for Non-Oxidative Methane Conversion Научная публикация
| Конференция |
9th International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts 10-14 сент. 2006 , Louvain-la-Neuve |
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| Сборник | Scientific Bases for the Preparation of Heterogeneous Catalysts Сборник, 2006. 1048 c. |
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| Журнал |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Вых. Данные | Год: 2006, Том: 162, Страницы: 913-920 Страниц : 8 DOI: 10.1016/S0167-2991(06)80997-3 | ||||
| Ключевые слова | clusters, high-silica zeolite, Keywords:synthesis, mesoporous, nanopowder | ||||
| Авторы |
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| Организации |
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Реферат:
A high-siliea ZSM-5 zeolite (SiO2/Al2O3=40) was synthesized and used to produce Mo-containing catalysts by different methods. Using the methods of high-resolution electron microscopy, energy dispersive X-ray spectrometry and thermoprogrammed ammonia desorption the composition and acidic properties of Mo-ZSM-5 catalysts were studied. The catalytic tests of the samples were carried out in the process of non-oxidative methane conversion at 750°C. It has been shown that two forms of molybdenum-containing particles are stabilized during the reaction: molybdenum carbide particles (of size 2-10 nm) located on the zeolite surface, and clusters (of size less than 1 nm) located inside its channels. It has been established that the clusters of oxidized molybdenum are the main sites of methane activation localized in open molecular pores of a zeolite
Библиографическая ссылка:
Vosmerikov A.V.
, Zaikovskii V.I.
, Korobitsyna L.L.
, Kodenev E.G.
, Kozlov V.V.
, Echevsky G.V.
Catalysts for Non-Oxidative Methane Conversion
В сборнике Scientific Bases for the Preparation of Heterogeneous Catalysts. 2006. – C.913-920. DOI: 10.1016/S0167-2991(06)80997-3 Scopus РИНЦ CAPlusCA OpenAlex
Catalysts for Non-Oxidative Methane Conversion
В сборнике Scientific Bases for the Preparation of Heterogeneous Catalysts. 2006. – C.913-920. DOI: 10.1016/S0167-2991(06)80997-3 Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 1 янв. 2006 г. |
| Опубликована online: | 2 сент. 2007 г. |
Идентификаторы БД:
| Scopus: | 2-s2.0-35248861542 |
| РИНЦ: | 13524539 |
| Chemical Abstracts: | 2008:289075 |
| Chemical Abstracts (print): | 151:35587 |
| OpenAlex: | W1542192994 |