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CFD Modeling of Compact Methanol Reformer Full article

Conference XXI International Conference on Chemical Reactors
22-25 Sep 2014 , Delft
Journal Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212
Output data Year: 2015, Volume: 282, Pages: 91-100 Pages count : 10 DOI: 10.1016/j.cej.2015.04.006
Tags CFD simulation, Fuel processor, Hydrogen, Methanol, Methanol steam reformer, Tubular reactor
Authors Klenov O.P. 1 , Makarshin L.L. 1 , Gribovskiy A.G. 1,2 , Andreev D.V. 1 , Parmon V.N. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akad. Lavrentieva 5, 630090 Novosibirsk, Russia
2 Novosibirsk State University, ul. Pirogova 2, 630090 Novosibirsk, Russia

Abstract: The compact fuel processor that uses methanol as a feedstock for the production of hydrogen and for temperature control was studied by computational fluid dynamics. The processor integrates in a single package the methanol–water evaporator, the gas flow distributors, the steam reformer and the methanol–air catalytic combustor. The reformer and the combustor were formed as tubular reactors that possessed a single metallic body like a monolith with an array of circular cross-section through-holes. Part of holes was filled with reforming catalyst and the other part was filled with a catalyst for the oxidation of methanol. The design provides efficient heat transfer between the reformer and the combustor and efficient temperature control of the reformer. The temperature distribution in the metallic body of the reformer and the combustor is almost uniform. The value of temperature nonuniformity does not exceed the value ΔT = 2.4% in any cross-section of the reaction zone. Maximum overall effectiveness of the fuel processor is achieved at the value of methanol feed equal 17.24 mmol/min (GHSV = 12,424 h−1) and 8.75 mmol/min (GHSV = 16,632 h−1) in the reformer and in the combustor, respectively. Under these conditions the hydrogen performance is equal to 70.0 l/h (48.7 mmol/min) and the temperature is equal to 286.4 °C in the reformer.
Cite: Klenov O.P. , Makarshin L.L. , Gribovskiy A.G. , Andreev D.V. , Parmon V.N.
CFD Modeling of Compact Methanol Reformer
Chemical Engineering Journal. 2015. V.282. P.91-100. DOI: 10.1016/j.cej.2015.04.006 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Apr 11, 2015
Published print: Dec 15, 2015
Identifiers:
Web of science: WOS:000362860100011
Scopus: 2-s2.0-84947862483
Elibrary: 24973670
Chemical Abstracts: 2015:662025
Chemical Abstracts (print): 163:413788
OpenAlex: W1972436720
Citing:
DB Citing
Web of science 24
Scopus 26
Elibrary 21
OpenAlex 29
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