Mathematic Modeling of the Process of Production of Nanofibrous Carbon from Methane in an Isothermal Reactor with a Fixed Bed of the Ni–Al2O3 Catalyst Научная публикация
| Журнал |
Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212 |
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| Вых. Данные | Год: 2006, Том: 120, Номер: 3, Страницы: 139-147 Страниц : 9 DOI: 10.1016/j.cej.2006.03.004 | ||||
| Ключевые слова | Filamentous carbon, Fixed catalyst bed, Ideal gas plugging, Methane decomposition, Nanofibrous carbon, Ni-Al2O3 catalyst, Reactor | ||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Российский фонд фундаментальных исследований | 04-03-32618 |
| 2 | Министерство образования и науки Российской Федерации | 203.06.03.001 |
Реферат:
The process of synthesis of nanofibrous carbon from methane achieved in an isothermal plug flow reactor with a fixed bed of catalyst 90 wt.% Ni–Al2O3 is considered. It is shown that the equations allow a solution in the form of a progressive wave of deactivation that moves at a constant rate and has a stationary profile. Analytic dependencies are obtained to calculate the wave rate and carbon content in the deactivated catalyst. The process parameters are calculated at 823 K and specific methane consumption 120 l/h g. The process parameters are compared for two types of reactors operating at identical conditions: a plug flow reactor with the fixed catalyst bed and a reactor with perfect mixing of catalyst particles and gas. The specific carbon yield is shown to be higher in the latter.
Библиографическая ссылка:
Zavarukhin S.G.
, Kuvshinov G.G.
Mathematic Modeling of the Process of Production of Nanofibrous Carbon from Methane in an Isothermal Reactor with a Fixed Bed of the Ni–Al2O3 Catalyst
Chemical Engineering Journal. 2006. V.120. N3. P.139-147. DOI: 10.1016/j.cej.2006.03.004 WOS Scopus РИНЦ CAPlusCA OpenAlex
Mathematic Modeling of the Process of Production of Nanofibrous Carbon from Methane in an Isothermal Reactor with a Fixed Bed of the Ni–Al2O3 Catalyst
Chemical Engineering Journal. 2006. V.120. N3. P.139-147. DOI: 10.1016/j.cej.2006.03.004 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 9 мар. 2005 г. |
| Принята к публикации: | 8 мар. 2006 г. |
| Опубликована online: | 6 июн. 2006 г. |
| Опубликована в печати: | 15 июл. 2006 г. |
Идентификаторы БД:
| Web of science: | WOS:000238876200001 |
| Scopus: | 2-s2.0-33745244272 |
| РИНЦ: | 13506242 |
| Chemical Abstracts: | 2006:595998 |
| Chemical Abstracts (print): | 145:106238 |
| OpenAlex: | W2054712400 |