Catalytic Hydrodechlorination of Hexachlorobenzene on Carbon Supported Pd-Ni Bimetallic Catalysts Full article
| Journal |
Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883 |
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| Output data | Year: 2003, Volume: 40, Number: 4, Pages: 293-304 Pages count : 12 DOI: 10.1016/S0926-3373(02)00156-X | ||||
| Tags | Bimetallic catalysts, Dechlorination, Hexachlorobenzene, Hydrodechlorination, Pd-Ni catalysts | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Siberian Branch of the Russian Academy of Sciences | |
| 2 | French National Centre for Scientific Research |
Abstract:
The study of the catalytic activity of carbon supported Pd-Ni catalysts for the hydrodechlorination of hexachlorobenzene was carried out in the liquid phase. The degree of dechlorination was found proportional to the surface Pd concentration, which is enhanced by the segregation of this element at the surface of the bimetallic particles. It is also shown that isolated Pd atoms located at the surface of Ni rich bimetallic particles are more active than those lying in larger ensembles. Finally bimetallic Pd-Ni catalysts containing only between 20 and 50 Pd atom%, although less active than pure Pd, lead to 75% of useful compounds, i.e. benzene, mono and dichlorobenzene.
Cite:
Simagina V.I.
, Likholobov V.A.
, Bergeret G.
, Gimenez M.
, Renouprez A.
Catalytic Hydrodechlorination of Hexachlorobenzene on Carbon Supported Pd-Ni Bimetallic Catalysts
Applied Catalysis B: Environmental. 2003. V.40. N4. P.293-304. DOI: 10.1016/S0926-3373(02)00156-X WOS Scopus РИНЦ ANCAN OpenAlex
Catalytic Hydrodechlorination of Hexachlorobenzene on Carbon Supported Pd-Ni Bimetallic Catalysts
Applied Catalysis B: Environmental. 2003. V.40. N4. P.293-304. DOI: 10.1016/S0926-3373(02)00156-X WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | May 9, 2002 |
| Accepted: | Jun 28, 2002 |
| Published online: | Oct 9, 2002 |
| Published print: | Feb 28, 2003 |
Identifiers:
| Web of science: | WOS:000181374900005 |
| Scopus: | 2-s2.0-0037469447 |
| Elibrary: | 13439881 |
| Chemical Abstracts: | 2003:125590 |
| Chemical Abstracts (print): | 138:403292 |
| OpenAlex: | W2067106255 |