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The Reaction Thermodynamics of Hydrogen Sulfide Decomposition into Hydrogen and Diatomic Sulfur Научная публикация

Журнал Journal of Sulfur Chemistry
ISSN: 1741-5993 , E-ISSN: 1741-6000
Вых. Данные Год: 2015, Том: 36, Номер: 3, Страницы: 234-239 Страниц : 6 DOI: 10.1080/17415993.2015.1010533
Ключевые слова diatomic sulfur, electronic structure, H2S decomposition, hydrogen production, hydrogen sulfide, reaction thermodynamics
Авторы Startsev A.N. 1 , Bulgakov N.N. 1 , Ruzankin S.Ph. 1 , Kruglyakova O.V. 1 , Paukshtis E.A. 1,2
Организации
1 Boreskov Institute of Catalysis, Novosibirsk, Russia
2 Tomsk State Universities, Tomsk, Russia

Реферат: To verify a hypothesis about the electronic state of diatomic gaseous sulfur formed during the lowtemperature catalytic decomposition of hydrogen sulfide, we carried out some experiments to examine elemental sulfur dissociation. As shown, after heating at ∼1000 K, elemental sulfur sealed in quartz ampoules with metal catalysts followed by quenching at room temperature did not produce any visible changes on solid sulfur. However, conversion of solid sulfur into gaseous diatomic sulfur can be realized via intermediate interaction of melted sulfur with hydrogen in the presence of Pt followed by decomposition of H2S formed on the surface of the metal catalyst at room temperature. It is suggested that the conversion of the singlet sulfur atoms into the ground triplet state becomes feasible only on the surface of metal catalysts resulted from the dissociation of hydrogen sulfide into adsorbed atomic species. 2 H2S Metal catalysts Room temperature 2 H2+ S2(gas)
Библиографическая ссылка: Startsev A.N. , Bulgakov N.N. , Ruzankin S.P. , Kruglyakova O.V. , Paukshtis E.A.
The Reaction Thermodynamics of Hydrogen Sulfide Decomposition into Hydrogen and Diatomic Sulfur
Journal of Sulfur Chemistry. 2015. V.36. N3. P.234-239. DOI: 10.1080/17415993.2015.1010533 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 8 июл. 2013 г.
Принята к публикации: 18 янв. 2015 г.
Опубликована online: 12 февр. 2015 г.
Опубликована в печати: 4 мая 2015 г.
Идентификаторы БД:
Web of science: WOS:000352628200001
Scopus: 2-s2.0-84939962435
РИНЦ: 24938907
Chemical Abstracts: 2015:273767
OpenAlex: W2083528834
Цитирование в БД:
БД Цитирований
Web of science 19
Scopus 19
РИНЦ 21
OpenAlex 21
Альметрики: