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Structured Catalysts for Steam/Autothermal Reforming of Biofuels on Heat-Conducting Substrates: Design and Performance Научная публикация

Конференция 7th Tokyo Conference on Advanced Catalytic Science and Technology
01-06 июн. 2014 , Kyoto
Журнал Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Вых. Данные Год: 2015, Том: 251, Страницы: 19-27 Страниц : 9 DOI: 10.1016/j.cattod.2014.10.045
Ключевые слова Biofuels reforming, Catalytic performance, Microchannel and foam substrates, Perovskite-like and fluorite-like oxide supports, Ru-Ni alloy nanoparticles, Structured catalysts
Авторы Sadykov V. 1,2 , Mezentseva N. 1,2 , Fedorova Yu. 1 , Lukashevich A. 1 , Pelipenko V. 1 , Kuzmin V. 1 , Simonov M. 1,2 , Ishchenko A. 1,2 , Vostrikov Z. 1 , Bobrova L. 1 , Sadovskaya E. 1,2 , Muzykantov V. 1 , Zadesenets A. 2,3 , Smorygo O. 4 , Roger A.-C. 5 , Parkhomenko K. 5
Организации
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
2 Novosibirsk State University, Novosibirsk 630090, Russia
3 Nikolayev Institute of Inorganic Chemistry, Novosibirsk 630090, Russia
4 Powder Metallurgy Institute, Minsk, Belarus
5 University of Strasbourg, France

Информация о финансировании (4)

1 Российский фонд фундаментальных исследований 12-03-93115
2 Сибирское отделение Российской академии наук 8
3 Министерство образования и науки Российской Федерации
4 European Commission 604296 FP7-NMP-2013-LARGE-7 BIOGO

Реферат: Catalysts for biofuels reforming based on two types of nanocomposite active components (Ni + Ru/La0.8Pr0.2Mn0.2Cr0.8O3/Y0.08Zr0.92O2−δ, Ni + Ru/Sm0.15Pr0.15Ce0.35Zr0.35O2) supported on microchannel substrates (Ni–Al alloy foam plates, Fechraloy plates protected by a thin corundum layer) were developed. Applied procedures for the active components loading on substrates provide thermochemical stability of supported layers of active components in tough operation conditions not affecting their reactivity/catalytic activity. Effects of the nature of nanocomposite active component, type of fuel (ethanol, ethyl acetate, acetone and glycerol), feed composition and contact time on the yield of syngas/byproducts and performance stability are considered and compared with results of calculations of the equilibrium composition of reaction mixtures. For nanocomposite active components with a high oxygen mobility and reactivity, reforming of such typical fuel as ethanol is described by the step-wise red-ox mechanism. Preliminary results of the mathematical modelling of the ethanol steam reforming on a stack of microchannel Fechraloy plates loaded with Ni + Ru/Sm0.15Pr0.15Ce0.35Zr0.35O2 active component revealed that this process can be satisfactorily described by the isothermal model without any impact of the heat/mass transfer.
Библиографическая ссылка: Sadykov V. , Mezentseva N. , Fedorova Y. , Lukashevich A. , Pelipenko V. , Kuzmin V. , Simonov M. , Ishchenko A. , Vostrikov Z. , Bobrova L. , Sadovskaya E. , Muzykantov V. , Zadesenets A. , Smorygo O. , Roger A.-C. , Parkhomenko K.
Structured Catalysts for Steam/Autothermal Reforming of Biofuels on Heat-Conducting Substrates: Design and Performance
Catalysis Today. 2015. V.251. P.19-27. DOI: 10.1016/j.cattod.2014.10.045 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 30 июл. 2014 г.
Принята к публикации: 19 окт. 2014 г.
Опубликована online: 20 нояб. 2014 г.
Опубликована в печати: 1 авг. 2015 г.
Идентификаторы БД:
Web of science: WOS:000354137000005
Scopus: 2-s2.0-84929121164
РИНЦ: 24029096
Chemical Abstracts: 2014:1951737
Chemical Abstracts (print): 163:10149
OpenAlex: W2038323760
Цитирование в БД:
БД Цитирований
Web of science 26
Scopus 26
РИНЦ 25
OpenAlex 24
Альметрики: