Reactions of 2,3-Naphthalenediol with Cyclohexane in the Presence of Aluminum Halides Научная публикация
| Журнал |
Tetrahedron Letters
ISSN: 0040-4039 |
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| Вых. Данные | Год: 2015, Том: 56, Номер: 17, Страницы: 2254-2257 Страниц : 4 DOI: 10.1016/j.tetlet.2015.03.059 | ||||||
| Ключевые слова | Ionic hydrogenation, Naphthols, Superacids, Superelectrophiles | ||||||
| Авторы |
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| Организации |
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Реферат:
2,3-Naphthalenediol (7) undergoes selective ionic hydrogenation with cyclohexane in the presence of excess AlCl3 or AlBr3 to afford 5,6,7,8-tetrahydro-2,3-naphthalenediol (8). Compound 8 can be further converted into 5,6,7,8-tetrahydro-1,2-naphthalenediol (9) and pyrocatechol (10). The discovered reactions represent new and efficient synthetic approaches to produce difficult to obtain derivatives of 7. The mechanistic aspects of the reactions, and the potential involvement of superelectrophilic dicationic intermediates, are discussed.
Библиографическая ссылка:
Zhu Z.
, Ostashevskaya L.A.
, Koltunov K.Y.
Reactions of 2,3-Naphthalenediol with Cyclohexane in the Presence of Aluminum Halides
Tetrahedron Letters. 2015. V.56. N17. P.2254-2257. DOI: 10.1016/j.tetlet.2015.03.059 WOS Scopus РИНЦ OpenAlex CAPlusCA
Reactions of 2,3-Naphthalenediol with Cyclohexane in the Presence of Aluminum Halides
Tetrahedron Letters. 2015. V.56. N17. P.2254-2257. DOI: 10.1016/j.tetlet.2015.03.059 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 28 янв. 2015 г. |
| Принята к публикации: | 13 мар. 2015 г. |
| Опубликована online: | 19 мар. 2015 г. |
| Опубликована в печати: | 1 апр. 2015 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000353745900031 |
| ≡ Scopus: | 2-s2.0-84937763215 |
| ≡ РИНЦ: | 23992199 |
| ≡ OpenAlex: | W1963850969 |
| ≡ Chemical Abstracts: | 2015:511011 |
| ≡ Chemical Abstracts (print): | 162:514135 |