BINOL Modification via SnAr Reactions with Pentafluoropyridine | Sciact - CRIS-system of Boreskov Institute of Catalysis

BINOL Modification via SnAr Reactions with Pentafluoropyridine Full article

Journal

Mendeleev Communications
ISSN: 0959-9436 , E-ISSN: 1364-551X

Output data

Year: 2015, Volume: 25, Number: 1, Pages: 39-40 Pages count : 2 DOI: 10.1016/j.mencom.2015.01.014

Tags

CATALYSIS; LIGANDS

Authors

Koltunov Konstantin Yu. ^1,2 , Chernov Aleksey N. ^2,3

Affiliations

1	G.K.Boreskov Institute of Catalysis, Siberian Branch of teh Russian Academy of Sciences
2	Department of Natutral Sciences, Novosibirsk State University
3	V.S. Sobolev Institute of Geology and Mineralogy SB RAS

(R)- and (S)-binaphthyl-2,2’-diols (BINOLs) smoothly react with pentafluoropyridine without racemization to give (R)- and (S)-2,2’- bis(tetrafluoropyridin-4-yloxy)-1,1’-binaphthyls. The 2(6)-positioned pyridine fluorine atoms can be replaced with amino moieties by reactions with amines.

Koltunov K.Y. , Chernov A.N.
BINOL Modification via SnAr Reactions with Pentafluoropyridine
Mendeleev Communications. 2015. V.25. N1. P.39-40. DOI: 10.1016/j.mencom.2015.01.014 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 31, 2014
Published print:	Jan 1, 2015
Published online:	Jan 28, 2015

Web of science:	WOS:000349879400014
Scopus:	2-s2.0-84921862175
Elibrary:	23969994
Chemical Abstracts:	2015:222757
Chemical Abstracts (print):	162:327046
OpenAlex:	W2040836298

DB	Citing
Web of science	6
Scopus	7
Elibrary	5
OpenAlex	6