The Properties of Capillary Columns with Sorbents Based on Poly-(1-Trimethylsilyl-1-Propyne) Modified with Nitrous Oxide | Sciact - CRIS-система Института катализа

The Properties of Capillary Columns with Sorbents Based on Poly-(1-Trimethylsilyl-1-Propyne) Modified with Nitrous Oxide Научная публикация

Журнал

Journal of Chromatography A
ISSN: 0021-9673 , E-ISSN: 1873-3778

Вых. Данные

Год: 2015, Том: 1406, Страницы: 291-298 Страниц : 8 DOI: 10.1016/j.chroma.2015.06.013

Ключевые слова

Capillary column, Gas-solid chromatography, Modified stationary phase, Poly-(1-trimethylsilyl-1-propyne) (PTMSP)

Авторы

Patrushev Yuri V. ^1,2 , Yakovleva Elena Y. ^1,2 , Shundrina Inna K ³ , Ivanov Dmitry P. ¹ , Glazneva Tatyana S. ^1,2

Организации

1	Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Pirogova Str., 2, Novosibirsk 630090, Russia
3	N.N. Vorozhtsov Institute of Organic Chemistry, pr. Lavrentieva 9, Novosibirsk 630090, Russia

Информация о финансировании (1)

Министерство образования и науки Российской Федерации

In this work, we report the study of properties of capillary columns with a porous layer of the functionalized polymer prepared via oxidation of poly-(1-trimethylsilyl-1-propyne) (PTMSP) by nitrous oxide. It was shown that the double C=C bonds of polymer reacted with nitrous oxide with formation of ketone, carbonyl and hydroxyl groups. The increase in number of those groups in polymer changed a polarity of PTMSP. The change in polarity of polymer led to the selectivity of separations, including oxygen-containing substances. The polarity values were calculated for the prepared columns. It was shown that the total polarity according to McReynolds (dI) was lower than that for known porous polymers.The examples of separations of aliphatic and aromatic hydrocarbons, oxygen- and halogen-containing substances were presented.

Patrushev Y.V. , Yakovleva E.Y. , Shundrina I.K. , Ivanov D.P. , Glazneva T.S.
The Properties of Capillary Columns with Sorbents Based on Poly-(1-Trimethylsilyl-1-Propyne) Modified with Nitrous Oxide
Journal of Chromatography A. 2015. V.1406. P.291-298. DOI: 10.1016/j.chroma.2015.06.013 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex

Поступила в редакцию:	6 апр. 2015 г.
Принята к публикации:	7 июн. 2015 г.
Опубликована online:	17 июн. 2015 г.
Опубликована в печати:	1 авг. 2015 г.

Web of science:	WOS:000358094200034
Scopus:	2-s2.0-84937631559
РИНЦ:	23991981
Chemical Abstracts:	2015:1367660
Chemical Abstracts (print):	163:344732
PMID (PubMed):	26105779
OpenAlex:	W644628921

БД	Цитирований
Web of science	19
Scopus	20
РИНЦ	23
OpenAlex	24