Template-Free Sol-Gel Synthesis of Catalytically Active Mesoporous Aluminosilicates Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2015, Volume: 56, Number: 4, Pages: 501-508 Pages count : 8 DOI: 10.1134/S0023158415040011 | ||||||
| Tags | mesoporous aluminosilicates, olefin oligomerization, porosity, sol-gel synthesis, surface acidity | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 14-03-97021 |
Abstract:
A template-free sol-gel synthesis method has been developed for obtaining mesoporous alumino-silicates with a narrow pore size distribution. The effect of the synthesis conditions on the formation of the porous structure and on the phase composition and surface acidity of the aluminosilicates has been elucidated. The catalytic properties of the synthesized aluminosilicates with SiO2/Al2O3 = 20 in the oligomerization of α-methylstyrene and 1-octene have been investigated. The highest oligomerization activity is shown by the aluminosilicate synthesized in two steps. The mesoporous aluminosilicates far exceed zeolite H-Beta (SiO2/Al2O3 = 18) in activity and in selectivity toward products with a higher degree of oligomerization.
Cite:
Agliullin M.R.
, Grigor’eva N.G.
, Danilova I.G.
, Magaev O.V.
, Vodyankina O.V.
Template-Free Sol-Gel Synthesis of Catalytically Active Mesoporous Aluminosilicates
Kinetics and Catalysis. 2015. V.56. N4. P.501-508. DOI: 10.1134/S0023158415040011 WOS Scopus РИНЦ AN OpenAlex
Template-Free Sol-Gel Synthesis of Catalytically Active Mesoporous Aluminosilicates
Kinetics and Catalysis. 2015. V.56. N4. P.501-508. DOI: 10.1134/S0023158415040011 WOS Scopus РИНЦ AN OpenAlex
Original:
Аглиуллин М.Р.
, Григорьева Н.Г.
, Данилова И.Г.
, Магаев О.В.
, Водянкина О.В.
Золь–гель синтез каталитически активных мезопористых алюмосиликатов без использования темплатов
Кинетика и катализ. 2015. Т.56. №4. С.507-514. DOI: 10.7868/S0453881115040012 РИНЦ OpenAlex
Золь–гель синтез каталитически активных мезопористых алюмосиликатов без использования темплатов
Кинетика и катализ. 2015. Т.56. №4. С.507-514. DOI: 10.7868/S0453881115040012 РИНЦ OpenAlex
Dates:
| Submitted: | Oct 31, 2014 |
| Published print: | Jul 1, 2015 |
| Published online: | Jul 25, 2015 |
Identifiers:
| Web of science: | WOS:000358408700014 |
| Scopus: | 2-s2.0-84937949752 |
| Elibrary: | 23993227 |
| Chemical Abstracts: | 2015:1234250 |
| OpenAlex: | W1949286591 |