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Wet Peroxide Oxidation of Phenol over Cu-ZSM-5 Catalyst in a Flow Reactor. Kinetics and Diffusion Study Full article

Conference XXI International Conference on Chemical Reactors
22-25 Sep 2014 , Delft
Journal Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212
Output data Year: 2015, Volume: 282, Pages: 108-115 Pages count : 8 DOI: 10.1016/j.cej.2015.02.064
Tags Catalytic wet peroxide oxidation, Cu-ZSM-5, Diffusion, Flow reactor, Kinetics, Phenol
Authors Taran Oxana P. 1,2 , Zagoruiko Andrey N. 1,2,4,5 , Ayusheev Artemiy B. 1 , Yashnik Svetlana A. 1 , Prihodʹko Roman V. 3 , Ismagilov Zinfer R. 1 , Goncharuk Vladislav V. 3 , Parmon Valentin N. 1,4
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Lavrentieva, Novosibirsk 630090, Russia
2 Novosibirsk State Technical University, 20 prosp. K. Marx, 20, Novosibirsk 630092, Russia
3 Dumansky Institute of Colloid and Water Chemistry, National Academy of Sciences of Ukraine, 42 blv. Vernadskogo, Kiev-142 03680, Ukraine
4 Novosibirsk State University, 2 St. Pirogova, Novosibirsk 630090, Russia
5 Tomsk Polytechnic University, 30, St. Lenina, Tomsk 634050, Russia

Funding (3)

1 Russian Foundation for Basic Research 12-03-90404
2 Russian Science Foundation 14-13-01155
3 Council for Grants of the President of the Russian Federation НШ-1183.2014.3

Abstract: The wet peroxide oxidation of phenol over the extruded 1.5%Cu/(80%H-ZSM-5 + 20%Al2O3) catalysts of the different geometric forms and sizes (cylinders with diameters 1, 2, 3 mm, trefoils, spheres and monoliths with size of channels 1.0 × 1.0, 1.5 × 1.5 mm) was studied in a flow reactor. The geometric form and size of the catalyst granules exert a pronounced effect on the apparent kinetics of the process. The highest efficiency toward phenol destruction was observed for the catalysts with a greater geometric surface area (trefoils and monolith with high channel density). The conversions of phenol and TOC at flow rate 5 mL min−1 equal to 100 and ∼90% were achieved over these catalysts. Application of the spherical shape catalyst with lowest geometric surface gave only 80% conversion of phenol at the same reaction conditions. The proposed mathematical model of the process, accounting for internal and external diffusion limitations on the base of the pseudo-first order simplification of the apparent kinetic rates, provide reasonably accurate description of the experimental data and reproducing all important process regularities.
Cite: Taran O.P. , Zagoruiko A.N. , Ayusheev A.B. , Yashnik S.A. , Prihodʹko R.V. , Ismagilov Z.R. , Goncharuk V.V. , Parmon V.N.
Wet Peroxide Oxidation of Phenol over Cu-ZSM-5 Catalyst in a Flow Reactor. Kinetics and Diffusion Study
Chemical Engineering Journal. 2015. V.282. P.108-115. DOI: 10.1016/j.cej.2015.02.064 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Feb 24, 2015
Published print: Dec 15, 2015
Identifiers:
Web of science: WOS:000362860100013
Scopus: 2-s2.0-84947870837
Elibrary: 24973702
Chemical Abstracts: 2015:355041
Chemical Abstracts (print): 163:415105
OpenAlex: W2001919839
Citing:
DB Citing
Web of science 42
Scopus 48
Elibrary 54
OpenAlex 46
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