Calculation of Microchannel Parameters in Aluminophosphate Zeolites Научная публикация
| Журнал |
Microporous and Mesoporous Materials
ISSN: 1387-1811 , E-ISSN: 1873-3093 |
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| Вых. Данные | Год: 2015, Том: 208, Страницы: 36-43 Страниц : 8 DOI: 10.1016/j.micromeso.2015.01.031 | ||
| Ключевые слова | fragment, Henry constants for H2 adsorption at 77 K, Isopotential surface of H2 adsorption, Model of the AlPO zeolite structure, Potential of paired adsorption interaction, Real shape and volume of microchannels | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский фонд фундаментальных исследований | 14-03-31372 |
Реферат:
Adsorption interaction of molecular hydrogen with framework atoms of aluminophosphate zeolites AlPO-5, -11, -8 and -36 were analyzed using a representative fragment of the structure with the volume about 32 nm3. Isopotential surfaces of the interaction between molecules were calculated. Isopotential surfaces with zero adsorption potential outline the shape of microchannels. Theoretical values of the zeolite microchannel volumes were calculated. Places for preferential localization of the sorbate molecules in the zeolite structure (places with the lowest adsorption potential) were determined for the Henry adsorption isotherm range. Calculated and experimental values of Henry constants for hydrogen adsorption at 77 K were compared.
Библиографическая ссылка:
Grenev I.V.
, Gavrilov V.Y.
Calculation of Microchannel Parameters in Aluminophosphate Zeolites
Microporous and Mesoporous Materials. 2015. V.208. P.36-43. DOI: 10.1016/j.micromeso.2015.01.031 WOS Scopus РИНЦ CAPlusCA OpenAlex
Calculation of Microchannel Parameters in Aluminophosphate Zeolites
Microporous and Mesoporous Materials. 2015. V.208. P.36-43. DOI: 10.1016/j.micromeso.2015.01.031 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 12 дек. 2014 г. |
| Принята к публикации: | 21 янв. 2015 г. |
| Опубликована online: | 29 янв. 2015 г. |
| Опубликована в печати: | 1 мая 2015 г. |
Идентификаторы БД:
| Web of science: | WOS:000352927000004 |
| Scopus: | 2-s2.0-84922521906 |
| РИНЦ: | 23132646 |
| Chemical Abstracts: | 2015:196168 |
| Chemical Abstracts (print): | 162:358913 |
| OpenAlex: | W1978338845 |