Role of Vanadium Species in the Selective Oxidation of Ethanol on V2O5/TiO2 Catalysts Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2013, Volume: 54, Number: 6, Pages: 730-734 Pages count : 5 DOI: 10.1134/S0023158413060128 | ||||
Tags | Vanadium; Vanadium Oxide; Ethanol Oxidation; Vanadium Content; Differential Dissolution | ||||
Authors |
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Affiliations |
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Funding (1)
1 | The Ministry of Education and Science of the Russian Federation |
Abstract:
The catalytic properties of a sample of 20% V2O5/TiO2 and its derivative, 12% V2O5/TiO2, which was obtained by the treatment of the catalyst with nitric acid and did not contain bulk V2O5 species, were compared. In spite of a significant difference in the vanadium contents, the activity of both of the samples in the process of the gas-phase aerobic oxidation of ethanol to acetaldehyde and acetic acid was found to be the same. It was hypothesized that a monolayer of vanadium oxide on the surface of TiO2 made the main contribution to the catalytic activity.
Cite:
Sobolev V.I.
, Danilevich E.V.
, Koltunov K.Y.
Role of Vanadium Species in the Selective Oxidation of Ethanol on V2O5/TiO2 Catalysts
Kinetics and Catalysis. 2013. V.54. N6. P.730-734. DOI: 10.1134/S0023158413060128 WOS Scopus РИНЦ ANCAN OpenAlex
Role of Vanadium Species in the Selective Oxidation of Ethanol on V2O5/TiO2 Catalysts
Kinetics and Catalysis. 2013. V.54. N6. P.730-734. DOI: 10.1134/S0023158413060128 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Соболев В.И.
, Данилевич Е.В.
, Колтунов К.Ю.
Роль ванадиевых форм в процессе селективного окисления этанола на катализаторах V2O5/TiO2
Кинетика и катализ. 2013. Т.54. №6. С.771-775. DOI: 10.7868/S0453881113060129 РИНЦ OpenAlex
Роль ванадиевых форм в процессе селективного окисления этанола на катализаторах V2O5/TiO2
Кинетика и катализ. 2013. Т.54. №6. С.771-775. DOI: 10.7868/S0453881113060129 РИНЦ OpenAlex
Dates:
Submitted: | Oct 1, 2012 |
Published print: | Nov 1, 2013 |
Published online: | Nov 15, 2013 |
Identifiers:
Web of science: | WOS:000327091100013 |
Scopus: | 2-s2.0-84892159036 |
Elibrary: | 21466140 |
Chemical Abstracts: | 2013:1786102 |
Chemical Abstracts (print): | 160:35414 |
OpenAlex: | W1993043785 |