Low-Temperature Oxidation Of Carbon Monoxide on Pd(Pt)/CeO2 Catalysts Prepared from Complex Salts | Sciact - CRIS-система Института катализа

Low-Temperature Oxidation Of Carbon Monoxide on Pd(Pt)/CeO2 Catalysts Prepared from Complex Salts Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2011, Том: 52, Номер: 2, Страницы: 282-295 Страниц : 14 DOI: 10.1134/S0023158411020182

Ключевые слова

Palladium; High Resolution Trans Mission Electron Microscopy; Cerium Oxide; High Resolution Trans Mission Electron Microscopy Image; Cerium Dioxide

Авторы

Slavinskaya E.M. ¹ , Gulyaev R.V. ¹ , Stonkus O.A. ^1,3 , Zadesenets A.V. ^2,3 , Plyusnin P.E. ^2,3 , Shubin Y.V. ^2,3 , Korenev S.V. ^2,3 , Ivanova A.S. ¹ , Zaikovskii V.I. ¹ , Danilova I.G. ¹ , Boronin A.I. ^1,3

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
2	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
3	Novosibirsk State University, Novosibirsk, 630090, Russia

Catalysts containing cerium oxide as a support and platinum and palladium as active components for the low-temperature oxidation of carbon monoxide were studied. The catalysts were synthesized in accordance with original procedures with the use of palladium and platinum complex salts. Regardless of preparation procedure, the samples prepared with the use of only platinum precursors did not exhibit activity at a low temperature because only metal and oxide (PtO, PtO2) nanoparticles were formed on the surface of CeO2. Unlike platinum, palladium can be dispersed on the surface of CeO2 to a maximum extent up to an almost an ionic (atomic) state, and it forms mixed surface phases with cerium oxide. In a mixed palladium-platinum catalyst, the ability of platinum to undergo dispersion under the action of palladium also increased; as a result, a combined surface phase with the formula Pd x Pt y CeO2 − δ, which exhibits catalytic activity at low temperatures, was formed.

Slavinskaya E.M. , Gulyaev R.V. , Stonkus O.A. , Zadesenets A.V. , Plyusnin P.E. , Shubin Y.V. , Korenev S.V. , Ivanova A.S. , Zaikovskii V.I. , Danilova I.G. , Boronin A.I.
Low-Temperature Oxidation Of Carbon Monoxide on Pd(Pt)/CeO2 Catalysts Prepared from Complex Salts
Kinetics and Catalysis. 2011. V.52. N2. P.282-295. DOI: 10.1134/S0023158411020182 WOS Scopus РИНЦ CAPlusCA OpenAlex

Славинская Е.М. , Гуляев Р.В. , Стонкус О.А. , Задесенец А.В. , Плюснин П.Е. , Шубин Ю.В. , Коренев С.В. , Иванова А.С. , Зайковский В.И. , Данилова И.Г. , Боронин А.И.
Исследование низкотемпературного окисления СО на катализаторах Pd(Pt)/CeO2, приготовленных из комплексных солей
Кинетика и катализ. 2011. Т.52. №2. С.291-304. РИНЦ

Поступила в редакцию:	2 июл. 2010 г.
Опубликована в печати:	1 мар. 2011 г.
Опубликована online:	7 апр. 2011 г.

Web of science:	WOS:000289254900019
Scopus:	2-s2.0-79953857005
РИНЦ:	17003184
Chemical Abstracts:	2011:438061
Chemical Abstracts (print):	156:540925
OpenAlex:	W1993385812

БД	Цитирований
Web of science	19
Scopus	18
РИНЦ	18
OpenAlex	19