Реферат: Radically different dependences of the activity of La1 − x Sr x MnO3 (x = 0−0.5) perovskites in methane oxidation on the degree of substitution of strontium for lanthanum are observed for low and high temperatures. Unsubstituted LaMnO3 exhibits the highest activity in the temperature range from 300 to 500°C, while the sample with the maximum degree of substitution (La0.5Sr0.5MnO3) shows the highest activity at higher temperatures of 700–900°C. In the low temperature region, the activity of La1t - x Sr x MnO3 is determined by the amount of weakly bound (overstoichiometric) oxygen, which is formed in cation-deficient lattices and is characterized by a thermal desorption peak with T max = 705°C. At higher temperatures (800–900°C), the strongly bound oxygen of the catalyst lattice is involved in the formation of the reaction products under both unsteady- and steady-state conditions. As a consequence, the catalytic activity in methane oxidation correlates with the apparent rate constant of oxygen diffusion in the oxide bulk.

Библиографическая ссылка: Ivanov D.V. , Pinaeva L.G. , Sadovskaya E.M. , Isupova L.A.
Influence of the Mobility of Oxygen on the Reactivity of La1 – xSrxMnO3 Perovskites in Methane Oxidation
Kinetics and Catalysis. 2011. V.52. N3. P.401-408. DOI: 10.1134/S0023158411030086 WOS Scopus РИНЦ CAPlusCA OpenAlex

Оригинальная: Иванов Д.В. , Пинаева Л.Г. , Садовская Е.М. , Исупова Л.А.
Влияние подвижности кислорода на реакционную способность перовскитов состава La1-xSrxMnO3 в реакции окисления метана
Кинетика и катализ. 2011. Т.52. №3. С.410-418. РИНЦ

Даты:

Поступила в редакцию:	23 апр. 2010 г.
Опубликована в печати:	1 мая 2011 г.
Опубликована online:	8 июн. 2011 г.

Идентификаторы БД:

Web of science:	WOS:000291397200010
Scopus:	2-s2.0-79959497761
РИНЦ:	16984656
Chemical Abstracts:	2011:709716
Chemical Abstracts (print):	155:406751
OpenAlex:	W1973868412

Цитирование в БД:

БД	Цитирований
Web of science	29
Scopus	27
РИНЦ	28
OpenAlex	31

Альметрики: