Ethylene Polymerization over Supported Titanium-Magnesium Catalysts: Effect of Polymerization Parameters on the Molecular Weight Distribution of Polyethylene Научная публикация
| Журнал |
Journal of Applied Polymer Science
ISSN: 0021-8995 , E-ISSN: 1097-4628 |
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| Вых. Данные | Год: 2011, Том: 122, Номер: 5, Страницы: 3092-3101 Страниц : 10 DOI: 10.1002/app.34203 | ||
| Ключевые слова | kinetics (polym.), molecular weight distribution/molar mass distribution, polyethylene (PE), polymer synthesis and characterization, Ziegler-Natta polymerization | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский фонд фундаментальных исследований | 10-03-00136 |
Реферат:
The data on the effects of polymerization duration, cocatalyst, and monomer concentrations upon ethylene polymerization in the absence of hydrogen, and the effect of an additional chain transfer agent (hydrogen) on the molecular weight (MW), molecular weight distribution (MWD), and content of vinyl terminal groups for polyethylene (PE) produced over the supported titanium-magnesium catalyst (TMC) are obtained. The effects of these parameters on nonuniformity of active sites for different chain transfer reactions are analyzed by deconvolution of the experimental MWD curves into Flory components. It has been shown that the polymer MW grows, the MWD becomes narrower and the content of vinyl terminal groups in PE increases with increasing polymerization duration. It is assumed to occur due to the reduction of the rate of chain transfer with AlEt3 with increasing polymerization duration. The polydispersity of PE is found to rise with increasing AlEt3 concentration and decreasing monomer concentration due to the emergence of additional low molecular weight Flory components. The ratios of the individual rate constants of chain transfer with AlEt3, monomer and hydrogen to the propagation rate constant have been calculated.
Библиографическая ссылка:
Nikolaeva M.I.
, Mikenas T.B.
, Matsko M.A.
, Echevskaya L.G.
, Zakharov V.A.
Ethylene Polymerization over Supported Titanium-Magnesium Catalysts: Effect of Polymerization Parameters on the Molecular Weight Distribution of Polyethylene
Journal of Applied Polymer Science. 2011. V.122. N5. P.3092-3101. DOI: 10.1002/app.34203 WOS Scopus РИНЦ CAPlusCA OpenAlex
Ethylene Polymerization over Supported Titanium-Magnesium Catalysts: Effect of Polymerization Parameters on the Molecular Weight Distribution of Polyethylene
Journal of Applied Polymer Science. 2011. V.122. N5. P.3092-3101. DOI: 10.1002/app.34203 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 14 окт. 2010 г. |
| Принята к публикации: | 24 янв. 2011 г. |
| Опубликована online: | 7 июл. 2011 г. |
| Опубликована в печати: | 5 дек. 2011 г. |
Идентификаторы БД:
| Web of science: | WOS:000295538600030 |
| Scopus: | 2-s2.0-80052395142 |
| РИНЦ: | 18003541 |
| Chemical Abstracts: | 2011:854633 |
| Chemical Abstracts (print): | 155:484544 |
| OpenAlex: | W2119623772 |