Effect of Crystalline Modification of the Support on the Reduction and Catalytic Properties of Cu/ZrO2 Catalysts in the Steam Reforming of Bioethanol Full article
| Journal |
Theoretical and Experimental Chemistry
ISSN: 0040-5760 , E-ISSN: 1573-935X |
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| Output data | Year: 2011, Volume: 47, Number: 5, Pages: 324-330 Pages count : 7 DOI: 10.1007/s11237-011-9222-x | ||||
| Tags | bioethanol, catalyst, copper, steam reforming, temperature-programmed reduction, zirconium dioxide | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 09-03-90406 |
| 2 | State Fund for Fundamental Research of Ukraine | F28/267-2009 |
Abstract:
A study was carried out on the steam reforming of bioethanol (15 vol.% ethanol in water) at 250–500 °C on copper catalysts supported on ZrO2 of the monoclinic (Z) and yttrium-stabilized tetragonal crystalline modifications (YSZ). Copper nanoparticles in such catalysts have similar reactivity regardless of the copper content and crystalline modification of the support. Cu/YSZ is highly selective relative to CO2, which may be related to enhanced mobility of oxygen in the support in the presence of Y2O3 stabilizing additive.
Cite:
Dolgikh L.Y.
, Pyatnitskii Y.I.
, Reshetnikov S.I.
, Deinega I.V.
, Staraya L.A.
, Moroz E.M.
, Strizhak P.E.
Effect of Crystalline Modification of the Support on the Reduction and Catalytic Properties of Cu/ZrO2 Catalysts in the Steam Reforming of Bioethanol
Theoretical and Experimental Chemistry. 2011. V.47. N5. P.324-330. DOI: 10.1007/s11237-011-9222-x WOS Scopus РИНЦ ANCAN OpenAlex
Effect of Crystalline Modification of the Support on the Reduction and Catalytic Properties of Cu/ZrO2 Catalysts in the Steam Reforming of Bioethanol
Theoretical and Experimental Chemistry. 2011. V.47. N5. P.324-330. DOI: 10.1007/s11237-011-9222-x WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Долгих Л.Ю.
, Пятницкий Ю.И.
, Решетников С.И.
, Дейнега И.В.
, Старая Л.А.
, Мороз Э.М.
, Стрижак П.Е.
Влияние кристаллической модификации носителя на восстановление и каталитические свойства катализаторов Cu/ZrO2 в реакции парового риформинга биоэтанола
Теоретическая и экспериментальная химия. 2011. Т.47. №5. С.309-314. РИНЦ
Влияние кристаллической модификации носителя на восстановление и каталитические свойства катализаторов Cu/ZrO2 в реакции парового риформинга биоэтанола
Теоретическая и экспериментальная химия. 2011. Т.47. №5. С.309-314. РИНЦ
Dates:
| Submitted: | Jul 27, 2011 |
| Accepted: | Sep 23, 2011 |
| Published print: | Oct 1, 2011 |
| Published online: | Nov 24, 2011 |
Identifiers:
| Web of science: | WOS:000300146200007 |
| Scopus: | 2-s2.0-82555195996 |
| Elibrary: | 18016142 |
| Chemical Abstracts: | 2011:1557020 |
| Chemical Abstracts (print): | 156:640434 |
| OpenAlex: | W2078516052 |