New Approach to the Synthesis of tris(Perfluoroalkyl)borane Adducts with Dialkylamines | Sciact - CRIS-system of Boreskov Institute of Catalysis

New Approach to the Synthesis of tris(Perfluoroalkyl)borane Adducts with Dialkylamines Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2011, Volume: 81, Number: 3, Pages: 509-516 Pages count : 8 DOI: 10.1134/S107036321103011X

Tags

Borane; General Chemistry; Magnesium Sulfate; Dichloro; Diethylamino

Authors

Adonin N.Y. ¹ , Bardin V.V. ² , Flörke U. ³ , Fron H. ⁴

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Lavrent’eva 5, Novosibirsk, 630090 Russia
2	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3	Paderborn University, Germany
4	Duisburg-Essen University, Germany

A convenient synthetic approach to the adducts (C n F2n+1)3BNHR2 (n = 2–4, 6; R = Me, Et) was developed, based on the reaction of lithium perfluoroalkyls with dichloro(dialkylamino)boranes at temperatures below −90°C. The target products can be synthesized with preparative yields of 50–90%.

Adonin N.Y. , Bardin V.V. , Flörke U. , Fron H.
New Approach to the Synthesis of tris(Perfluoroalkyl)borane Adducts with Dialkylamines
Russian Journal of General Chemistry. 2011. V.81. N3. P.509-516. DOI: 10.1134/S107036321103011X WOS Scopus РИНЦ ANCAN OpenAlex

Адонин Н.Ю. , Бардин В.В. , Flörke U. , Fron H.
Новый синтетический подход к аддуктам трис (перфторалкил) борана с диалкиламинами
Журнал общей химии. 2011. Т.81. №3. С.413-420. РИНЦ

Submitted:	Jun 29, 2010
Published print:	Mar 1, 2011
Published online:	Apr 20, 2011

Web of science:	WOS:000289738600011
Scopus:	2-s2.0-79955149559
Elibrary:	17001506
Chemical Abstracts:	2011:488024
Chemical Abstracts (print):	155:12040
OpenAlex:	W1994640825

DB	Citing
Web of science	7
Scopus	6
Elibrary	7
OpenAlex	8