Chromatographic Properties of Poly(1-trimethylsilyl-1-propyne) Full article
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Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
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| Output data | Year: 2011, Volume: 85, Number: 5, Pages: 851-856 Pages count : 6 DOI: 10.1134/S0036024411050049 | ||
| Tags | adsorption, column efficiency, desorption, gas chromatography, mesopores, micropores, polymer | ||
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Abstract:
Changes in the properties of the surface of poly(1-trimethylsilyl-1-propyne) (PTMSP) over time were studied by gas chromatography combined with adsorption under static conditions. It was ascertained that a reduction in the volume of micropores in a polymer results in the sorption-desorption processes occurring preferentially in mesopores. The formation of a more chemically uniform surface leads to a considerable increase in the symmetry of chromatographic peaks and the efficiency of a column. These changes allow us to broaden the range of compounds analyzed on columns with PTMSP.
Cite:
Belotserkovskaya V.Y.
, Yakovleva E.Y.
Chromatographic Properties of Poly(1-trimethylsilyl-1-propyne)
Russian Journal of Physical Chemistry A. 2011. V.85. N5. P.851-856. DOI: 10.1134/S0036024411050049 WOS Scopus РИНЦ ANCAN OpenAlex
Chromatographic Properties of Poly(1-trimethylsilyl-1-propyne)
Russian Journal of Physical Chemistry A. 2011. V.85. N5. P.851-856. DOI: 10.1134/S0036024411050049 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Белоцерковская В.Ю.
, Яковлева Е.Ю.
Хроматографические свойства поли(1-триметилсилил-1-пропина)
Журнал физической химии. 2011. Т.85. №5. С.939-944. РИНЦ
Хроматографические свойства поли(1-триметилсилил-1-пропина)
Журнал физической химии. 2011. Т.85. №5. С.939-944. РИНЦ
Dates:
| Submitted: | Nov 10, 2009 |
| Published online: | Apr 8, 2011 |
| Published print: | May 1, 2011 |
Identifiers:
| Web of science: | WOS:000289292400021 |
| Scopus: | 2-s2.0-79955800698 |
| Elibrary: | 16984167 |
| Chemical Abstracts: | 2011:437875 |
| Chemical Abstracts (print): | 154:502798 |
| OpenAlex: | W2007297119 |