MIL-101 Supported Polyoxometalates: Synthesis, Characterization and Catalytic Applications in Selective Liquid-Phase Oxidation Review
| Journal |
Israel Journal of Chemistry
ISSN: 0021-2148 , E-ISSN: 1869-5868 |
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| Output data | Year: 2011, Volume: 51, Number: 2, Pages: 281-289 Pages count : 9 DOI: 10.1002/ijch.201000082 | ||||
| Tags | heterogeneous catalysis, metal-organic framework, MIL-101, selective oxidation, supported polyoxometalate | ||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 09-03-12112 |
| 2 | Russian Foundation for Basic Research | 09-03-93109 |
| 3 | Siberian Branch of the Russian Academy of Sciences | 107 |
Abstract:
In this short review paper, we survey our recent achievements in the preparation of heterogeneous catalysts via incorporation of polyoxometalates (POMs) within cages of the mesoporous coordination polymer MIL-101, their physicochemical characterization, and application for liquidphase selective oxidation of organic compounds with green oxidants — O2 and aqueous H2O2. Special attention is paid to analyze a manifestation of confinement effects and to address the issues of catalytic activity and selectivity after immobilization and after recycling, catalyst resistance to POM leaching, and the nature of catalysis. The scope and limitations of POM/MIL-101 catalysts are discussed.
Cite:
Maksimchuk N.V.
, Kholdeeva O.A.
, Kovalenko K.A.
, Fedin V.P.
MIL-101 Supported Polyoxometalates: Synthesis, Characterization and Catalytic Applications in Selective Liquid-Phase Oxidation
Israel Journal of Chemistry. 2011. V.51. N2. P.281-289. DOI: 10.1002/ijch.201000082 WOS Scopus РИНЦ OpenAlex ANCAN
MIL-101 Supported Polyoxometalates: Synthesis, Characterization and Catalytic Applications in Selective Liquid-Phase Oxidation
Israel Journal of Chemistry. 2011. V.51. N2. P.281-289. DOI: 10.1002/ijch.201000082 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Dec 18, 2010 |
| Accepted: | Jan 13, 2011 |
| Published online: | Feb 17, 2011 |
| Published print: | Mar 1, 2011 |
Identifiers:
| ≡ Web of science: | WOS:000289121100011 |
| ≡ Scopus: | 2-s2.0-79952794678 |
| ≡ Elibrary: | 16721793 |
| ≡ OpenAlex: | W2029212365 |
| ≡ Chemical Abstracts: | 2011:346369 |
| ≡ Chemical Abstracts (print): | 154:434063 |