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Influence of TiO2 on the Efficiency of Low–Temperature Generation of H2 from Solid–Phase Compositions Based on NH3BH3 Full article

Journal Chemistry for Sustainable Development
ISSN: 1817-1818
Output data Year: 2014, Volume: 22, Number: 6, Pages: 603-611 Pages count : 9
Tags AMMINBORANE, TITANIUM DIOXIDE, THERMOLYSIS, HYDROTHERMOLYSIS, WATER ADSORPTION
Authors Kayl N.L. 1 , Komova O.V. 1 , Netskina O.V. 1 , Odegova G.V. 1 , Ozerova A.M. 1 , Simagina V.I. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5, Lavrent'ev prospect, Novosibirsk, 630090

Abstract: Low-temperautre hydrogen generation from solid-phase compositions based on amminborane (NH3BH3) and TiO2 under external heating to 80 °C depending on the physicochemical properties of titanium dioxide, its content in the composition and the amount of adsorbed water was studied. It was established that the maximal yield and rate of hydrogen formation are achieved for the system prepared on the basis of fine titanium dioxide witht eh participation of adsorbed water. It is assumed that an increase in the efficiency of hydrogen obtaining from the composition in comparison with initial hydride is due to a conjugation of the exothermal process of amminborane hydrolysis with its dehydrogenation (thermolysis).
Cite: Kayl N.L. , Komova O.V. , Netskina O.V. , Odegova G.V. , Ozerova A.M. , Simagina V.I.
Influence of TiO2 on the Efficiency of Low–Temperature Generation of H2 from Solid–Phase Compositions Based on NH3BH3
Chemistry for Sustainable Development. 2014. V.22. N6. P.603-611. РИНЦ
Original: Кайль Н.Л. , Комова О.В. , Нецкина О.В. , Одегова Г.В. , Озерова А.М. , Симагина В.И.
Влияние TiO2 на эффективность низкотемпературной генерации H2 из твердофазных композиций на основе NH3BH3
Химия в интересах устойчивого развития. 2014. Т.22. №6. С.603-611. RSCI РИНЦ ANCAN
Identifiers:
Elibrary: 30762073
Citing: Пока нет цитирований