Pyrolysis of Liquid Hexadecane with Selective Microwave Heating of the Catalyst | Sciact - CRIS-система Института катализа

Pyrolysis of Liquid Hexadecane with Selective Microwave Heating of the Catalyst Научная публикация

Журнал

Theoretical and Experimental Chemistry
ISSN: 0040-5760 , E-ISSN: 1573-935X

Вых. Данные

Год: 2011, Том: 46, Номер: 6, Страницы: 384-392 Страниц : 9 DOI: 10.1007/s11237-011-9169-y

Ключевые слова

α-olefins, hexadecane, microwave, pyrolysis

Авторы

Udalov E.I. ¹ , Bolotov V.A. ¹ , Tanashev Y.Y. ¹ , Chernousov Y.D. ² , Parmon V.N. ^1,3

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Prospekt Akademika Lavrent’eva, 5, Novosibirsk 630090, Russian Federation
2	Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Ul. Institutskaya, 3, Novosibirsk 630090, Russian Federation
3	Novosibirsk State University, Ul. Pirogova, 2, Novosibirsk 630090, Russian Federation

Информация о финансировании (3)

1	Сибирское отделение Российской академии наук	5
2	Президиум РАН	19.2
3	Совет по грантам Президента Российской Федерации	НШ-3156.2010.3

The pyrolysis of liquid n-hexadecane was studied on various catalysts with selective microwave (MW) heating of a catalyst possessing much greater microwave absorption capacity than the long-chain hydrocarbon studied. This method permits rapid heating of the catalyst to temperatures much higher than 400 °C, leading to reflux of the liquid substrate, movement of the catalyst granules within the substrate, and chemical transformations (cracking) of hexadecane. High pyrolysis selectivity relative to α-olefins was found on various catalysts such as magnetic microspheres (coal combustion ash), Al2O3/Al, and Pd/KTP (glass fiber). This behavior may be attributed to tempering of the primary products in the bulk of the liquid reagent. Furthermore, MW pyrolysis on magnetic microspheres was found to be accompanied by formation of rather thick carbon microfibers with diameter 300–500 nm.

Udalov E.I. , Bolotov V.A. , Tanashev Y.Y. , Chernousov Y.D. , Parmon V.N.
Pyrolysis of Liquid Hexadecane with Selective Microwave Heating of the Catalyst
Theoretical and Experimental Chemistry. 2011. V.46. N6. P.384-392. DOI: 10.1007/s11237-011-9169-y WOS Scopus РИНЦ CAPlusCA OpenAlex

Удалов Е.И. , Болотов В.А. , Танашев Ю.Ю. , Черноусов Ю.Д. , Пармон В.Н.
Пиролиз жидкого гексадекана в условиях селективного нагрева катализатора СВЧ-излучением
Теоретическая и экспериментальная химия. 2010. Т.46. №6. С.370-377. РИНЦ

Поступила в редакцию:	13 окт. 2010 г.
Опубликована в печати:	1 янв. 2011 г.
Опубликована online:	19 мар. 2011 г.

Web of science:	WOS:000288959700006
Scopus:	2-s2.0-79953200753
РИНЦ:	16983886
Chemical Abstracts:	2011:400325
Chemical Abstracts (print):	154:463676
OpenAlex:	W2143720631

БД	Цитирований
Web of science	10
Scopus	12
РИНЦ	10
OpenAlex	16