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Sinergistic Effect of Titanium Dioxide and Iron Oxide Aerosols in Adsorption and Photocatalytic Oxidation of Dimethyl Methylphosphonate. Full article

Journal Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X
Output data Year: 2015, Volume: 89, Number: 4, Pages: 693-698 Pages count : 6 DOI: 10.1134/S0036024415040044
Tags photocatalytic oxidation, synergism, TiO2 and FeOOH aerosol
Authors Besov A.S. 1,2 , Vorontsov A.V. 1
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk, Russia
2 Novosibirsk State University, Novosibirsk, Russia

Funding (5)

1 Russian Foundation for Basic Research 13-08-01286
2 Russian Foundation for Basic Research 15-08-01936
3 North Atlantic Treaty Organization SfP-981461
4 Organisation for the Prohibition of Chemical Weapons 187532/13
5 International Science and Technology Center 3305

Abstract: Kinetics of adsorption, dark and photocatalytic destruction of dimethyl methylphosphonate (DMMP) vapors was investigated on the surface of nanosized FeOOH (3 nm) and mixture of FeOOH with TiO2 (5 nm) (1 : 1) in aerosol state in a closed chamber. FeOOH aerosol adsorbs DMMP (100 ppm) with characteristic time 32 s and does not show photocatalytic activity. Adsorbed DMMP undergoes hydrolysis with formation of gaseous methanol with characteristic time 11 min, while mixed FeOOH–TiO2 aerosol adsorbs DMMP and converts it into CO and CO2 under the action of UV light.
Cite: Besov A.S. , Vorontsov A.V.
Sinergistic Effect of Titanium Dioxide and Iron Oxide Aerosols in Adsorption and Photocatalytic Oxidation of Dimethyl Methylphosphonate.
Russian Journal of Physical Chemistry A. 2015. V.89. N4. P.693-698. DOI: 10.1134/S0036024415040044 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Бесов А.С. , Воронцов А.В.
Синэргетический эффект при адсорбции и фотокаталитическом окислении паров диметилметилфосфоната в присутствии аэрозолей диоксида титана и оксида железа
Журнал физической химии. 2015. Т.89. №4. С.694-699. DOI: 10.7868/S0044453715040044 РИНЦ OpenAlex
Dates:
Submitted: May 21, 2014
Published online: Mar 17, 2015
Published print: Apr 1, 2015
Identifiers:
Web of science: WOS:000351447700021
Scopus: 2-s2.0-84925617741
Elibrary: 24019860
Chemical Abstracts: 2015:451678
Chemical Abstracts (print): 167:60720
OpenAlex: W2039121395
Citing:
DB Citing
Web of science 4
Scopus 4
Elibrary 3
OpenAlex 4
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