Transformations of 1-(2-Aminophenyl)propan-2-ol to 2-Methylindoline | Sciact - CRIS-system of Boreskov Institute of Catalysis

Transformations of 1-(2-Aminophenyl)propan-2-ol to 2-Methylindoline Full article

Journal

Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X

Output data

Year: 2015, Volume: 145, Pages: 955-963 Pages count : 9 DOI: 10.1007/s10562-014-1474-3

Tags

Acidity, Alcohols, Amines, Zeolites

Authors

Bernas Heidi ¹ , Demidova Yuliya S. ^2,3 , Aho Atte ¹ , Simakova Irina L. ^2,3 , Kumar Narendra ¹ , Laribi Yosra ⁴ , Perrichon Philippe ⁴ , Leino Reko ⁵ , Murzin Dmitry Yu. ¹

Affiliations

1	Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, Abo Akademi University, Biskopsgatan 8, 20500 Turku, Finland
2	Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia
3	Novosibirsk State University, 630090 Novosibirsk, Russia
4	Sanofi-Aventis Recherche & Developpement, Centre de Recherche de Vitry-sur-Seine 13, Vitry-sur-Seine, France
5	Laboratory of Organic Chemistry, Abo Akademi University, Biskopsgatan 8, 20500 Turku, Finland

Funding (2)

1	European Commission	246095 FP7-NMP-2009-LARGE-3 POLYCAT
2	Åbo Akademi University

The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200 C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to 2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.

Bernas H. , Demidova Y.S. , Aho A. , Simakova I.L. , Kumar N. , Laribi Y. , Perrichon P. , Leino R. , Murzin D.Y.
Transformations of 1-(2-Aminophenyl)propan-2-ol to 2-Methylindoline
Catalysis Letters. 2015. V.145. P.955-963. DOI: 10.1007/s10562-014-1474-3 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Nov 21, 2014
Accepted:	Dec 29, 2014
Published online:	Jan 10, 2015
Published print:	Mar 1, 2015

Web of science:	WOS:000350677000026
Scopus:	2-s2.0-84938394654
Elibrary:	23995566
Chemical Abstracts:	2015:67471
Chemical Abstracts (print):	162:326791
OpenAlex:	W2080908063

DB	Citing
Web of science	2
Scopus	2
Elibrary	2
OpenAlex	2