Perovskite-Like Catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for Wet Peroxide Oxidation of Phenol | Sciact - CRIS-system of Boreskov Institute of Catalysis

Perovskite-Like Catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for Wet Peroxide Oxidation of Phenol Full article

Journal

Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883

Output data

Year: 2016, Volume: 180, Pages: 86-93 Pages count : 8 DOI: 10.1016/j.apcatb.2015.05.055

Tags

LaCuO3; LaFeO3; Perovskite-like oxides; Phenol; Wet peroxide oxidation

Authors

Taran Oxana P. ^1,2 , Ayusheev Artemiy B. ¹ , Ogorodnikova Olga L. ¹ , Prosvirin Igor P. ^1,3 , Isupova Lyubov A. ¹ , Parmon Valentin N. ^1,3

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, prosp. Lavrentieva, 5, 630090 Novosibirsk, Russia
2	Novosibirsk State Technical University, prosp. K. Marx, 20, Novosibirsk 630092, Russia
3	Novosibirsk State University, Pirogova st., 2, Novosibirsk 630090, Russia

Funding (1)

Russian Science Foundation

14-13-01155

The catalytic behavior of perovskite-like oxides LaBO3 (B = Cu, Fe, Co, Ni, Mn) prepared by the Pecini method were examined in wet peroxide oxidation of phenol as a model organic substrate. The study showed the activity of only LaCuO3 and LaFeO3 perovskite-like catalysts, Cu-containing catalysts being more active, though Fe-containing being more stable. The leaching test proved the heterogeneous nature of the catalyst action. The long-term experiments revealed the acceptable stability of the LaFeO3 catalyst. XRD studies of the spent samples demonstrated the stability of the perovskite-like structure of the catalysts during the reaction. The assumption about the nature of the active sites and the possible mechanism of the reaction was proposed based on of the XPS study.

Taran O.P. , Ayusheev A.B. , Ogorodnikova O.L. , Prosvirin I.P. , Isupova L.A. , Parmon V.N.
Perovskite-Like Catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for Wet Peroxide Oxidation of Phenol
Applied Catalysis B: Environmental. 2016. V.180. P.86-93. DOI: 10.1016/j.apcatb.2015.05.055 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 7, 2015
Accepted:	May 29, 2015
Published online:	Jun 12, 2015
Published print:	Jan 1, 2016

Web of science:	WOS:000362379800011
Scopus:	2-s2.0-84934962957
Elibrary:	24475775
Chemical Abstracts:	2015:1028788
Chemical Abstracts (print):	163:433062
OpenAlex:	W978985481

DB	Citing
Web of science	134
Scopus	146
Elibrary	145
OpenAlex	152