Chlorine Adsorption on Cu(111) Revisited: LT-STM and DFT Study | Sciact - CRIS-system of Boreskov Institute of Catalysis

Chlorine Adsorption on Cu(111) Revisited: LT-STM and DFT Study Full article

Journal

Surface Science
ISSN: 0039-6028

Output data

Year: 2015, Volume: 639, Pages: 7-12 Pages count : 6 DOI: 10.1016/j.susc.2015.03.030

Tags

Chlorine, Copper (111), Density functional theory, Lateral interactions, Scanning tunneling microscopy

Authors

Andryushechkin B.V. ¹ , Zheltov V.V. ¹ , Cherkez V. ^1,2 , Zhidomirov G.M. ^1,3 , Klimov A. ¹ , Kierren B. ² , Fagot-Revurat Y. ² , Malterre D. ² , Eltsov K.N. ^1,4

Affiliations

1	A.M. Prokhorov General Physics Institute, Russian Academy of Sciences, Vavilov str. 38, 119991 Moscow, Russia
2	Université de Lorraine, UMR CNRS 7198, Institut Jean Lamour, BP 239, 54506 Vandoeuvre-les-Nancy, France
3	G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Prospect Lavrentieva 5, 630090 Novosibirsk, Russia
4	Moscow Institute of Physics and Technology, Institutskii per. 9, 141700 Dolgoprudny, Moscow Region, Russia

Funding (1)

Russian Foundation for Basic Research

12-02-01188 (01201261320)

Adsorption of chlorine atoms on the Cu(111) surface has been studied with low-temperature scanning tunneling microscopy (LT-STM) in a combination with density functional theory (DFT) calculations. At submonolayer coverage range (θ ≤ 0.10 ML), chlorine forms quasi-one dimensional chains. Atoms in the chains alternately occupy fcc and hcp positions, with nearest-neighbor distance of ≈3.9 Å. At coverage of 0.10–0.33 ML, a simple structure is formed, in which all chlorine atoms occupy fcc positions with nearest neighbor distances of 4.4 Å.

Andryushechkin B.V. , Zheltov V.V. , Cherkez V. , Zhidomirov G.M. , Klimov A. , Kierren B. , Fagot-Revurat Y. , Malterre D. , Eltsov K.N.
Chlorine Adsorption on Cu(111) Revisited: LT-STM and DFT Study
Surface Science. 2015. V.639. P.7-12. DOI: 10.1016/j.susc.2015.03.030 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Oct 22, 2014
Accepted:	Mar 4, 2015
Published online:	Apr 13, 2015
Published print:	Sep 1, 2015

Web of science:	WOS:000356546000002
Scopus:	2-s2.0-84928537198
Elibrary:	24025104
Chemical Abstracts:	2015:692050
Chemical Abstracts (print):	162:635158
OpenAlex:	W2060395433

DB	Citing
Web of science	14
Scopus	16
Elibrary	15
OpenAlex	15