Insights into the Reactivity of La1−xSrxMnO3 (x = 0 ÷ 0.7) in High Temperature N2O Decomposition Научная публикация
| Журнал |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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| Вых. Данные | Год: 2011, Том: 141, Номер: 2, Страницы: 322-331 Страниц : 10 DOI: 10.1007/s10562-010-0503-0 | ||
| Ключевые слова | La-Sr-Mn mixed oxide, Layer-structured perovskite, Microdistortions, Nitrous oxide decomposition, Oxygen mobility, Polymorphic phase transition | ||
| Авторы |
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| Организации |
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Реферат:
In this paper a wide range of La1−x Sr x MnO3 (x = 0–0.7) perovskites was synthesized by Pechini route, characterized by XRD (including high temperature measurements), XPS, differential dissolution phase analysis, TPR H2, oxygen exchange and tested in N2O decomposition at 900 °C. At low degree of Sr substitution for La (x ≤ 0.3), high catalytic activity was found for perovskites with hexagonal structure (x = 0.1–0.2) and can be related to fast oxygen mobility caused by the lattice disordering during polymorphic phase transition from the hexagonal to cubic structure. For multiphase samples (x > 0.3) increase of activity and oxygen mobility can be attributed to the formation of the layer-structured perovskite–LaSrMnO4 on the surface.
Библиографическая ссылка:
Ivanov D.V.
, Pinaeva L.G.
, Isupova L.A.
, Nadeev A.N.
, Prosvirin I.P.
, Dovlitova L.S.
Insights into the Reactivity of La1−xSrxMnO3 (x = 0 ÷ 0.7) in High Temperature N2O Decomposition
Catalysis Letters. 2011. V.141. N2. P.322-331. DOI: 10.1007/s10562-010-0503-0 WOS Scopus РИНЦ CAPlusCA OpenAlex
Insights into the Reactivity of La1−xSrxMnO3 (x = 0 ÷ 0.7) in High Temperature N2O Decomposition
Catalysis Letters. 2011. V.141. N2. P.322-331. DOI: 10.1007/s10562-010-0503-0 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 2 сент. 2010 г. |
| Принята к публикации: | 11 нояб. 2010 г. |
| Опубликована online: | 30 нояб. 2010 г. |
| Опубликована в печати: | 1 февр. 2011 г. |
Идентификаторы БД:
| Web of science: | WOS:000287506500015 |
| Scopus: | 2-s2.0-79951945750 |
| РИНЦ: | 16684258 |
| Chemical Abstracts: | 2010:1490917 |
| Chemical Abstracts (print): | 154:218597 |
| OpenAlex: | W1980472319 |