Effect of the Nature of Carbon Support on the Formation of Active Sites in Pd/C and Ru/C Catalysts for Hydrogenation of Furfural | Sciact - CRIS-system of Boreskov Institute of Catalysis

Effect of the Nature of Carbon Support on the Formation of Active Sites in Pd/C and Ru/C Catalysts for Hydrogenation of Furfural Full article

Conference

6th International Symposium on Carbon for Catalysis
22-25 Jun 2014 , Trondheim

Journal

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Output data

Year: 2015, Volume: 249, Pages: 145-152 Pages count : 8 DOI: 10.1016/j.cattod.2014.10.037

Tags

Carbon supports, Catalytic hydrogenation, Furfural, Palladium catalysts, Ruthenium catalysts

Authors

Mironenko Roman M. ^1,2 , Belskaya Olga B. ^1,3 , Gulyaeva Tatyana I. ¹ , Nizovskii Alexander I. ^3,4 , Kalinkin Alexander V. ⁴ , Bukhtiyarov Valerii I. ⁴ , Lavrenov Alexander V. ¹ , Likholobov Vladimir A. ^1,5

Affiliations

1	Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, Neftezavodskaya Street, 54, 644040 Omsk, Russia
2	Omsk F.M. Dostoevsky State University, Pr. Mira, 55a, 644077 Omsk, Russia
3	Omsk State Technical University, Pr. Mira, 11, 644050 Omsk, Russia
4	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva, 5, 630090 Novosibirsk, Russia
5	Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences, Pr. Marksa, 15, 644024 Omsk, Russia

The study considered the formation and catalytic properties of the active sites in Pd/C and Ru/C catalysts supported on carbon nanotubes (CNT) and carbon black (CB). The nature of carbon support was shown to affect the dispersion of supported metal and its catalytic properties in the aqueous-phase hydrogenation of furfural. The 1.5% Pd/CB catalyst demonstrated a high selectivity (99%) for furfuryl alcohol during hydrogenation of furfural at a temperature of 50 °C and hydrogen pressure of 0.5 MPa. The 1.5% Pd/CNT catalyst was not active under mild conditions of the reaction (50 °C, 0.5 MPa), but had a greater tendency to reduce the furan ring under severe conditions (90 °C, 0.5 or 2.0 MPa) as demonstrated by an increased yield of tetrahydrofurfuryl alcohol. The ruthenium samples showed a low activity in aqueous-phase hydrogenation of furfural irrespective of the support nature and reaction conditions, possibly due to irreversible adsorption of water on the active sites.

Mironenko R.M. , Belskaya O.B. , Gulyaeva T.I. , Nizovskii A.I. , Kalinkin A.V. , Bukhtiyarov V.I. , Lavrenov A.V. , Likholobov V.A.
Effect of the Nature of Carbon Support on the Formation of Active Sites in Pd/C and Ru/C Catalysts for Hydrogenation of Furfural
Catalysis Today. 2015. V.249. P.145-152. DOI: 10.1016/j.cattod.2014.10.037 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 29, 2014
Accepted:	Oct 16, 2014
Published online:	Nov 15, 2014
Published print:	Jul 1, 2015

Web of science:	WOS:000352957100019
Scopus:	2-s2.0-84939979974
Elibrary:	24938979
Chemical Abstracts:	2014:1914372
Chemical Abstracts (print):	162:476740
OpenAlex:	W2056393088

DB	Citing
Web of science	93
Scopus	97
Elibrary	92
OpenAlex	99