Photoreactivity of Metal-Organic Frameworks in the Decolorization of Methylene Blue in Aqueous Solution | Sciact - CRIS-system of Boreskov Institute of Catalysis

Photoreactivity of Metal-Organic Frameworks in the Decolorization of Methylene Blue in Aqueous Solution Full article

Journal

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Output data

Year: 2016, Volume: 266, Pages: 136-143 Pages count : 8 DOI: 10.1016/j.cattod.2015.07.026

Tags

Band gap, Metal-organic frameworks, Methylene blue, Photocatalysis

Authors

Kozlova Ekaterina A. ^1,2,3 , Panchenko Valentina N. ^1,2 , Hasan Zubair ⁴ , Khan Namzul Abedin ⁴ , Timofeeva Maria N. ^1,2,5 , Jhung Sung Hwa ⁴

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090, Novosibirsk, Russian Federation
2	Novosibirsk State University, Pirogova Str. 2, 630090, Novosibirsk, Russian Federation
3	Research and Educational Center for Energy Efficient Catalysis in Novosibirsk National Research University, Pirogova Str. 2, 630090, Novosibirsk, Russian Federation
4	Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, Republic of Korea
5	Novosibirsk State Technical University, Prospekt K. Marksa 20, 630092, Novosibirsk, Russian Federation

Funding (8)

1	Federal Agency for Scientific Organizations	V.44.2.12.
2	Russian Foundation for Basic Research	15-33-20458
3	Russian Foundation for Basic Research	14-03-00854
4	Russian Foundation for Basic Research	14-05-00297
5	Council for Grants of the President of the Russian Federation	МК-3141.2015.3
6	Council for Grants of the President of the Russian Federation	НШ-1183.2014.3
7	Skolkovo Foundation	1 от 28.11.2013
8	Kyungpook National University

The effect of metal ions and functional groups in organic ligands on the photocatalytic properties of metal-carboxylates, such as isostructural MIL-100(M) (M = Al, Fe, V, and Cr), isoreticular UiO-66-R (R = H, NH2, and NO2), MIL-47(V), and MIL-125(Ti), was investigated using the decolorization of methylene blue in aqueous solution at pH 7.0 and 20 °C under UV radiation. The metal-carboxylates were characterized by diffuse reflectance UV/vis measurements. The determination of the band gap (Eg) on the basis of DR-UV/vis measurements showed that Eg values correlate with ionic covalent parameters, i.e., the strength of the interaction between metal and oxygen in the “M+n-O2− pair. According to DR-UV/vis spectroscopic and catalytic investigations, the reactivity of metal-carboxylates correlated with the band-gap value (Eg), which could be adjusted by varying the nature of the metal ions in SBUs or functional groups in the organic ligands.

Kozlova E.A. , Panchenko V.N. , Hasan Z. , Khan N.A. , Timofeeva M.N. , Jhung S.H.
Photoreactivity of Metal-Organic Frameworks in the Decolorization of Methylene Blue in Aqueous Solution
Catalysis Today. 2016. V.266. P.136-143. DOI: 10.1016/j.cattod.2015.07.026 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Apr 7, 2015
Accepted:	Jul 17, 2015
Published online:	Aug 14, 2015
Published print:	May 15, 2016

Web of science:	WOS:000372321100017
Scopus:	2-s2.0-84961189097
Elibrary:	27103842
Chemical Abstracts:	2015:1312486
Chemical Abstracts (print):	164:366455
OpenAlex:	W1141735954

DB	Citing
Web of science	34
Scopus	42
Elibrary	37
OpenAlex	38