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Length-Dependent Broadband Electric Properties of PMMA Composites Filled with Carbon Nanotubes Full article

Conference Compound Semiconductor Week 2015
28 Jun - 2 Jul 2015 , Santa Barbara
Journal Physica Status Solidi (A) Applications and Materials (after 2004)
ISSN: 1862-6300 , E-ISSN: 1862-6319
Output data Year: 2016, Volume: 213, Number: 4, Pages: 1025-1033 Pages count : 9 DOI: 10.1002/pssa.201532289
Tags carbon nanotubes, composite material, dielectric permittivity, percolation threshold
Authors Kranauskaite Ieva 1 , Macutkevic Jan 1 , Banys Juras 1 , Kuznetsov Vladimir L. 2,3,4 , Moseenkov Sergey I. 2 , Rudina Nina A. 2 , Krasnikov Dmitriy V. 2,3
Affiliations
1 Vilnius University, Sauletekio ave. 9, 10222 Vilnius, Lithuania
2 Boreskov Institute of Catalysis SB RAS, Lavrentieva ave. 5, Novosibirsk, Russia
3 Novosibirsk State University, Pirogova str. 2, Novosibirsk, Russia
4 Tomsk State University, Tomsk, Lenina Avenue 36, 634050 Tomsk Oblast, Russia

Funding (2)

1 The Ministry of Education and Science of the Russian Federation 14.607.21.0046 (RFMEFI60714X0046)
2 European Commission

Abstract: Broadband dielectric/electric properties of multiwalled carbon nanotubes (MWCNT) polymethylmetacrylate composites were studied in a wide temperature range (25–400 K). It was established that the percolation threshold is lower in composites with the shortest MWCNT, due to the better distribution of the MWCNT in the polymer matrix. The value of the dielectric permittivity and the electrical conductivity below the percolation threshold is also higher in composites with the shortest MWCNT. Below the percolation threshold the dielectric dispersion in composites is mainly related with the b relaxation in the polymer matrix. The length of the MWCNT and its concentration have also the huge influence on polymer matrix molecular dynamics, the relaxation time is shortest in composites with the higher MWCNT concentration and in composites with the shortest MWCNT. At low temperatures the conductivity of composites above the percolation threshold is governed by an electron tunneling between MWCNT clusters. At higher temperatures the electrical transport occurs also due to the finite electrical conductivity of the polymer matrix.
Cite: Kranauskaite I. , Macutkevic J. , Banys J. , Kuznetsov V.L. , Moseenkov S.I. , Rudina N.A. , Krasnikov D.V.
Length-Dependent Broadband Electric Properties of PMMA Composites Filled with Carbon Nanotubes
Physica Status Solidi (A) Applications and Materials (after 2004). 2016. V.213. N4. P.1025-1033. DOI: 10.1002/pssa.201532289 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Apr 27, 2015
Accepted: Nov 4, 2015
Published online: Dec 3, 2015
Published print: Apr 1, 2016
Identifiers:
Web of science: WOS:000374560100031
Scopus: 2-s2.0-84963701856
Elibrary: 27008485
Chemical Abstracts: 2015:1950205
OpenAlex: W2291163479
Citing:
DB Citing
Web of science 11
Scopus 11
Elibrary 12
OpenAlex 11
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