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Silicate Fiberglass Catalysts: From Science to Technology Full article

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2015, Volume: 7, Number: 4, Pages: 267-274 Pages count : 8 DOI: 10.1134/S2070050415040029
Tags deep oxidation of hydrocarbons, glass fiber, oxidative destruction of chlororganics, palladium, platinum, selective hydrogenation of acetylene
Authors Balʹzhinimaev B.S. 1 , Suknev A.P. 1 , Gulyaeva Y.K. 1 , Kovalyov E. V. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Abstract: Efficient methods for the confining of highly dispersed Pd and Pt particles 1–1.5 nm in size in the subsurface layers of silicate glass fibers at depths of 10–20 nm are developed. Fiberglass catalysts reveal high activity in the selective hydrogenation of acetylene and the deep oxidation of hydrocarbons despite their low metal contents (0.01–0.02 wt %). The monometallic Pd/FG catalyst thus exhibits higher C2H2 hydrogenation selectivity at high acetylene conversion (99%+) in comparison to the commercial bimetallic Pd–Ag catalyst, and the activity of the Pt/FG catalyst in the deep oxidation of organic and chlororganic compounds, including dioxins, is found to be higher than that of the commercial AP-56 (Pt/Al2O3) catalyst. The efficiency of Pt/FG has successfully been demonstrated in the removal volatile organic compounds (VOC) from Monomer plant of PJSC Nizhnekamskneftekhim for more than four years of continuous operation.
Cite: Balʹzhinimaev B.S. , Suknev A.P. , Gulyaeva Y.K. , Kovalyov E.V.
Silicate Fiberglass Catalysts: From Science to Technology
Catalysis in Industry. 2015. V.7. N4. P.267-274. DOI: 10.1134/S2070050415040029 WOS Scopus РИНЦ OpenAlex
Original: Бальжинимаев Б.С. , Сукнев А.П. , Гуляева Ю.К. , Ковалев Е.В.
Силикатные стекловолокнистые катализаторы: от науки к технологиям
Катализ в промышленности. 2015. Т.15. №4. С.22-29. DOI: 10.18412/1816-0387-2015-4-22-29 РИНЦ ANCAN OpenAlex
Dates:
Submitted: Apr 21, 2015
Published print: Oct 1, 2015
Published online: Dec 29, 2015
Identifiers:
Web of science: WOS:000372437900004
Scopus: 2-s2.0-84951861444
Elibrary: 26847178
OpenAlex: W2299698374
Citing:
DB Citing
Web of science 5
Scopus 7
Elibrary 5
OpenAlex 7
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