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Structure of Copper Oxide Species Supported on Monoclinic Zirconia Научная публикация

Журнал The Journal of Physical Chemistry C
ISSN: 1932-7447 , E-ISSN: 1932-7455
Вых. Данные Год: 2015, Том: 119, Номер: 52, Страницы: 28828-28835 Страниц : 8 DOI: 10.1021/acs.jpcc.5b06331
Ключевые слова Copper loadingCopper oxide speciesMonoclinic structuresMonoclinic zirconiaRadial distribution functions
Авторы Pakharukova Vera P. 1,2 , Moroz Ella M. 1 , Zyuzin Dmitry A. 1 , Ishchenko Arcady V. 1 , Dolgikh Lidiya Yu. 3 , Strizhak Peter E. 3
Организации
1 Boreskov Institute of Catalysis, SB RAS, Pr. Lavrentieva 5, 630090 Novosibirsk, Russia
2 Novosibirsk State University, Pirogova Str. 2, 630090 Novosibirsk, Russia
3 Pisarzhevskii Institute of Physical Chemistry of the NAS, Pr. Nauki 31, 03039 Kiev, Ukraine

Информация о финансировании (1)

1 Федеральное агентство научных организаций России V.44.1.17. (0303-2014-0003)

Реферат: The structure of copper oxide species in Cu/ZrO2 catalysts with monoclinic zirconia as a support was studied. The catalysts with various copper loadings (3–40 wt % of Cu) prepared by impregnation technique were characterized using N2O titration, X-ray diffraction (XRD) analysis, radial distribution function (RDF) of electron density, and high-resolution transmission electron microscopy (HRTEM). It was established that the Cu/ZrO2 catalysts contained highly dispersed CuO particles along with the large ones. Geometrical similarity between the CuO and ZrO2 monoclinic structures favors stabilization of the highly dispersed CuO particles on the support with low specific surface area.
Библиографическая ссылка: Pakharukova V.P. , Moroz E.M. , Zyuzin D.A. , Ishchenko A.V. , Dolgikh L.Y. , Strizhak P.E.
Structure of Copper Oxide Species Supported on Monoclinic Zirconia
The Journal of Physical Chemistry C. 2015. V.119. N52. P.28828-28835. DOI: 10.1021/acs.jpcc.5b06331 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 2 июл. 2015 г.
Принята к публикации: 14 дек. 2015 г.
Опубликована online: 22 дек. 2015 г.
Опубликована в печати: 31 дек. 2015 г.
Идентификаторы БД:
Web of science: WOS:000367704500016
Scopus: 2-s2.0-84953211387
РИНЦ: 26928865
Chemical Abstracts: 2015:1996774
Chemical Abstracts (print): 164:90409
OpenAlex: W2197882497
Цитирование в БД:
БД Цитирований
Web of science 37
Scopus 40
РИНЦ 36
OpenAlex 37
Альметрики: