Photocatalytic Hydrogen Evolution by Iridium(III)–Rhodium(III) System: Effect of the Free Ligand Addition Full article
| Journal |
International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487 |
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| Output data | Year: 2016, Volume: 41, Number: 4, Pages: 2592-2597 Pages count : 6 DOI: 10.1016/j.ijhydene.2015.12.096 | ||||||
| Tags | Catalyst design, Hydrogen evolution, Iridium, Pyridine derivatives, Rhodium | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 15-33-20458 |
| 2 | Federal Agency for Scientific Organizations | V.44.2.11. |
Abstract:
Rh(III) complexes of the general form {RhL4Cl2} with pyridine derivatives ligands (L) were used for the first time as water reduction catalysts in photocatalytic hydrogen generation process in pair with [Ir(ppy)2bpy]+ complex as a photosynthesizer. The efficiency of given Ir(III)–Rh(III) systems in the photocatalytic hydrogen generation process was found to be on the level of 20–30% which is corresponding to the highest currently achieved quantum efficiency values for homogeneous photocatalysts. Fast deactivation of the systems due to destruction of {RhL4Cl2} units was observed but it was suppressed via addition of extra amount of free L ligand in the reaction mixture. Quantum efficiency of modified in this manner [Ir(ppy)2bpy]+/{RhL4Cl2} systems achieved up to 80% value.
Cite:
Vasilchenko D.B.
, Tkachev S.V.
, Kurenkova A.Y.
, Kozlova E.A.
, Kozlov D.V.
Photocatalytic Hydrogen Evolution by Iridium(III)–Rhodium(III) System: Effect of the Free Ligand Addition
International Journal of Hydrogen Energy. 2016. V.41. N4. P.2592-2597. DOI: 10.1016/j.ijhydene.2015.12.096 WOS Scopus РИНЦ OpenAlex ANCAN
Photocatalytic Hydrogen Evolution by Iridium(III)–Rhodium(III) System: Effect of the Free Ligand Addition
International Journal of Hydrogen Energy. 2016. V.41. N4. P.2592-2597. DOI: 10.1016/j.ijhydene.2015.12.096 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Oct 26, 2015 |
| Accepted: | Dec 15, 2015 |
| Published online: | Jan 11, 2016 |
| Published print: | Jan 30, 2016 |
Identifiers:
| ≡ Web of science: | WOS:000370306300048 |
| ≡ Scopus: | 2-s2.0-84957840583 |
| ≡ Elibrary: | 27028257 |
| ≡ OpenAlex: | W2235396977 |
| ≡ Chemical Abstracts: | 2016:21054 |
| ≡ Chemical Abstracts (print): | 164:228983 |