Effect of Boron on Acid and Catalytic Properties of Pd-ZSM-23/Al2O3 Catalysts in the Reaction of Diesel Fuel Hydroisomerization Full article
| Journal |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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| Output data | Year: 2015, Volume: 88, Number: 11, Pages: 1827-1838 Pages count : 12 DOI: 10.1134/S10704272150110142 | ||
| Tags | Zeolite; Boron; Boron Concentration; Acid Center; Pour Point | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | V.46.2.7. |
Abstract:
Effect of the concentration and introduction method of boron on the acid characteristics and catalytic
properties of Pd-ZSM-23/Al2O3 catalysts in hydroisomerization of diesel fuel was studied. It was found that raising
the concentration of introduced boron in a support results in that the concentration of acid centers, specifi c
surface area, and volume of micropores in the catalysts nonlinearly decrease. To obtain the optimal acidity it is
primarily necessary to reduce the concentration of excessively strong Lewis acid centers in zeolites and also to
reach a moderate concentration of Brønsted acid centers. The best catalytic properties are observed for the catalyst
containing 0.5 wt % boron
Cite:
Uvarkina D.D.
, Piryutko L.V.
, Danilova I.G.
, Budukva S.V.
, Klimov O.V.
, Kharitonov A.S.
, Noskov A.S.
Effect of Boron on Acid and Catalytic Properties of Pd-ZSM-23/Al2O3 Catalysts in the Reaction of Diesel Fuel Hydroisomerization
Russian Journal of Applied Chemistry. 2015. V.88. N11. P.1827-1838. DOI: 10.1134/S10704272150110142 WOS Scopus РИНЦ OpenAlex ANCAN
Effect of Boron on Acid and Catalytic Properties of Pd-ZSM-23/Al2O3 Catalysts in the Reaction of Diesel Fuel Hydroisomerization
Russian Journal of Applied Chemistry. 2015. V.88. N11. P.1827-1838. DOI: 10.1134/S10704272150110142 WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Уваркина Д.Д.
, Пирютко Л.В.
, Данилова И.Г.
, Будуква С.В.
, Климов О.В.
, Харитонов А.С.
, Носков А.С.
Влияние бора на кислотные и каталитические свойства катализаторов Pd-ZSM-23/Al2O3 в реакции гидроизомеризации дизельного топлива
Журнал прикладной химии. 2015. Т.88. №11. С.1613-1625. РИНЦ
Влияние бора на кислотные и каталитические свойства катализаторов Pd-ZSM-23/Al2O3 в реакции гидроизомеризации дизельного топлива
Журнал прикладной химии. 2015. Т.88. №11. С.1613-1625. РИНЦ
Dates:
| Published print: | Nov 1, 2015 |
| Submitted: | Nov 13, 2015 |
| Published online: | Feb 17, 2016 |
Identifiers:
| ≡ Web of science: | WOS:000370279700014 |
| ≡ Scopus: | 2-s2.0-84958214766 |
| ≡ Elibrary: | 26844163 |
| ≡ OpenAlex: | W2298246784 |
| ≡ Chemical Abstracts: | 2016:272461 |
| ≡ Chemical Abstracts (print): | 164:340128 |