Effect of Precursor on the Catalytic Properties of Ni2P/SiO2 in Methyl Palmitate Hydrodeoxygenation | Sciact - CRIS-system of Boreskov Institute of Catalysis

Effect of Precursor on the Catalytic Properties of Ni2P/SiO2 in Methyl Palmitate Hydrodeoxygenation Full article

Journal

RSC Advances
ISSN: 2046-2069

Output data

Year: 2016, Volume: 6, Pages: 30372 - 30383 Pages count : 12 DOI: 10.1039/c6ra01171c

Tags

Atomic emission spectroscopy; Catalyst activity; Catalysts; Chemical analysis; Nickel; Nickel compounds; Organometallics; Palmitic acid; Phosphorus; Silica; Solutions

Authors

Shamanaev Ivan V. ^1,2,3 , Deliy Irina V. ^1,2,3 , Aleksandrov Pavel V. ^1,3 , Gerasimov Evgeny Yu. ^1,2,3 , Pakharukova Vera P. ^1,2,3 , Kodenev Evgeny G. ¹ , Ayupov Artem B. ^1,2 , Andreev Andrey S. ¹ , Lapina Olga B. ¹ , Bukhtiyarova Galina A. ¹

Affiliations

1	Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Pirogova st. 2, Novosibirsk, 630090, Russia
3	Research and Educational Center for Energy Efficient Catalysis, Novosibirsk National Research University, Pirogova st. 2, Novosibirsk, 630090, Russia

Funding (1)

Federal Agency for Scientific Organizations

V.45.3.2.

The effect of phosphorus precursor on the physicochemical and catalytic properties of silica-supported nickel phosphide catalysts in the hydrodeoxygenation (HDO) of aliphatic model compound methyl palmitate (C15H31COOCH3) has been considered. Nickel acetate (Ni(OAc)2) and diammonium hydrogen phosphate ((NH4)2HPO4) (phosphate precursor) or nickel hydroxide (Ni(OH)2) and phosphorous acid (H3PO3) (phosphite precursor) have been used for the catalyst preparation by incipient wetness impregnation of SiO2 with an aqueous solution of the precursors, followed by temperature-programmed reduction in hydrogen flow. Chemical analysis (ICP-AES), H2-TPR, NH3-TPD, 31P MAS NMR, XRD, and TEM have been employed for the characterization of the catalysts. The optimal reduction parameters of the silica-supported nickel phosphide catalysts have been found for the phosphate and phosphite precursors in terms of their activity in methyl palmitate HDO. The Ni2P/SiO2 catalysts prepared by the phosphite method have shown higher catalytic activity in comparison with the Ni2P/SiO2 catalysts prepared by the phosphate method. The activity has been shown to depend on the catalyst handling after reduction: in situ reduced catalysts demonstrate higher conversion of methyl palmitate than the samples exposed to the reduction, passivation and re-reduction steps.

Shamanaev I.V. , Deliy I.V. , Aleksandrov P.V. , Gerasimov E.Y. , Pakharukova V.P. , Kodenev E.G. , Ayupov A.B. , Andreev A.S. , Lapina O.B. , Bukhtiyarova G.A.
Effect of Precursor on the Catalytic Properties of Ni2P/SiO2 in Methyl Palmitate Hydrodeoxygenation
RSC Advances. 2016. V.6. P.30372 - 30383. DOI: 10.1039/c6ra01171c WOS Scopus РИНЦ AN OpenAlex

Submitted:	Jan 14, 2016
Accepted:	Mar 16, 2016
Published online:	Mar 18, 2016

Web of science:	WOS:000373061600060
Scopus:	2-s2.0-85012912615
Elibrary:	29483651
Chemical Abstracts:	2016:442018
OpenAlex:	W2298276544

DB	Citing
Web of science	24
Scopus	26
Elibrary	24
OpenAlex	24