Effect of Water on Decomposition of Formic Acid over V–Ti Oxide Catalyst: Kinetic and in situ FTIR Study Научная публикация
| Журнал |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Вых. Данные | Год: 2012, Том: 357, Страницы: 148-153 Страниц : 6 DOI: 10.1016/j.molcata.2012.02.005 | ||
| Ключевые слова | Formic acid decomposition, In situ FTIR, Kinetics, V-Ti oxide catalyst, Water | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский фонд фундаментальных исследований | 11-03-00584 |
Реферат:
Decomposition of formic acid over V–Ti oxide catalyst in the absence and in the presence of water was studied by kinetic and in situ FTIR methods. CO and CO2 in a ratio of ∼9/1 are the products of decomposition of formic acid. Surface bidentate and monodentate formate ions are the products of formic acid adsorption at 120–140 °C. Decrease in the rate of formic acid decomposition in the presence of water observed in the steady-state kinetic experiments is related with the competitive adsorption between H2O and formic acid and with the acceleration of the reverse reaction of formic acid formation from formates.
Библиографическая ссылка:
Popova G.Y.
, Chesalov Y.A.
, Sadovskaya E.M.
, Andrushkevich T.V.
Effect of Water on Decomposition of Formic Acid over V–Ti Oxide Catalyst: Kinetic and in situ FTIR Study
Journal of Molecular Catalysis A: Chemical. 2012. V.357. P.148-153. DOI: 10.1016/j.molcata.2012.02.005 WOS Scopus РИНЦ CAPlusCA OpenAlex
Effect of Water on Decomposition of Formic Acid over V–Ti Oxide Catalyst: Kinetic and in situ FTIR Study
Journal of Molecular Catalysis A: Chemical. 2012. V.357. P.148-153. DOI: 10.1016/j.molcata.2012.02.005 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 28 июн. 2011 г. |
| Принята к публикации: | 6 февр. 2012 г. |
| Опубликована online: | 14 февр. 2012 г. |
| Опубликована в печати: | 1 мая 2012 г. |
Идентификаторы БД:
| Web of science: | WOS:000302664000021 |
| Scopus: | 2-s2.0-84858441498 |
| РИНЦ: | 17980519 |
| Chemical Abstracts: | 2012:416097 |
| Chemical Abstracts (print): | 156:402794 |
| OpenAlex: | W1992136696 |