Influence of Particle Size on the Magnetic Properties of Copper(II) Nitrate Complex with 2-(N-Acetylamino)-6-Methylpyridine Научная публикация
| Журнал |
Applied Magnetic Resonance
ISSN: 0937-9347 , E-ISSN: 1613-7507 |
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| Вых. Данные | Год: 2015, Том: 46, Номер: 2, Страницы: 337-347 Страниц : 11 DOI: 10.1007/s00723-014-0637-0 | ||||||
| Ключевые слова | Coordination compounds Copper nitrate complexes Crystalline samples Electron paramagnetic resonances (EPR) Frozen solutions Mesoporous structures Nano-sized particles Single crystal X-ray diffraction analysis | ||||||
| Авторы |
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| Организации |
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Информация о финансировании (4)
| 1 | Российский фонд фундаментальных исследований | 12-03-31343 |
| 2 | Российский фонд фундаментальных исследований | 14-03-31539 |
| 3 | Российский фонд фундаментальных исследований | 14-03-90006 |
| 4 | Министерство образования и науки Российской Федерации | 02.740.11.0628 |
Реферат:
The coordination compound of copper nitrate [CuL2(H2O)](NO3)2 with 2-(N-acetylamino)-6-methylpyridine (L) of the composition [CuL2(H2O)](NO3)2 has been prepared and investigated by single-crystal X-ray diffraction analysis and electron paramagnetic resonance (EPR) measurements. Crystalline samples, frozen solution in ethanol, thin films on quartz substrates and nanosized particles in mesoporous structures were investigated. The observed EPR spectra of [CuL2(H2O)](NO3)2 with a mesoporous structure and a pore diameter of 4 nm demonstrates that only dimers are realized in this matrix, but in a mesoporous structure with a pore diameter of 9 nm, seed crystals are formed together with dimers.
Библиографическая ссылка:
Antonova O.V.
, Nadolinny V.A.
, Berezin S.A.
, Lider E.V.
, Lavrenova L.G.
, Melgunov M.S.
Influence of Particle Size on the Magnetic Properties of Copper(II) Nitrate Complex with 2-(N-Acetylamino)-6-Methylpyridine
Applied Magnetic Resonance. 2015. V.46. N2. P.337-347. DOI: 10.1007/s00723-014-0637-0 WOS Scopus РИНЦ CAPlusCA OpenAlex
Influence of Particle Size on the Magnetic Properties of Copper(II) Nitrate Complex with 2-(N-Acetylamino)-6-Methylpyridine
Applied Magnetic Resonance. 2015. V.46. N2. P.337-347. DOI: 10.1007/s00723-014-0637-0 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 7 авг. 2014 г. |
| Опубликована online: | 8 янв. 2015 г. |
| Опубликована в печати: | 1 мар. 2015 г. |
Идентификаторы БД:
| Web of science: | WOS:000350284300008 |
| Scopus: | 2-s2.0-84925462818 |
| РИНЦ: | 24019665 |
| Chemical Abstracts: | 2015:115471 |
| Chemical Abstracts (print): | 163:251353 |
| OpenAlex: | W2094014105 |