Theoretical and Experimental Study of Methane Partial Oxidation to Syngas in Catalytic Membrane Reactor with Asymmetric Oxygen-Permeable Membrane | Sciact - CRIS-system of Boreskov Institute of Catalysis

Theoretical and Experimental Study of Methane Partial Oxidation to Syngas in Catalytic Membrane Reactor with Asymmetric Oxygen-Permeable Membrane Full article

Conference

12th International Conference on Catalysis in Membrane Reactors
22-25 Jun 2015 , Szczecin

Journal

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Output data

Year: 2016, Volume: 268, Pages: 103-110 Pages count : 8 DOI: 10.1016/j.cattod.2016.01.005

Tags

Catalytic membrane reactor, Mathematical modeling, Mixed ionic-electronic conductivity, Nanocomposites, Oxygen-permeable membrane, Partial oxidation of methane, Syngas production

Authors

Shelepova E. ^1,2 , Vedyagin A. ^1,2 , Sadykov V. ^1,3 , Mezentseva N. ^1,3 , Fedorova Y. ¹ , Smorygo O. ⁴ , Klenov O. ¹ , Mishakov I. ^1,2,3

Affiliations

1	Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Science, Pr. Ac. Lavrentieva, 5, Novosibirsk 630090, Russian Federation
2	National Research Tomsk Polytechnic University, Lenin Avenue, 30, Tomsk, 634050, Russian Federation
3	Novosibirsk State University, Pirogova str., 2, Novosibirsk 630090, Russian Federation
4	Institute of Powder Metallurgy, Platonov str., 41, Minsk 220005, Belarus

Funding (2)

1	Federal Agency for Scientific Organizations	V.45.3.2.
2	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO

This paper presents results of theoretical and experimental research concerning synthesis of multilayer asymmetric oxygen-permeable membrane and its application for partial oxidation of methane. The membrane is based on macroporous Ni-Al foam substrate with three layers of perovskite-fluorite nanocomposites with graded (meso-micro) porosity, thin dense MnFe2O4–Ce0.9Gd0.1O2 layer and porous layer of LaNi0.9Pt0.1O3/Pr0.3Ce0.35Zr0.35O2-x catalyst. Testing of membrane in methane partial oxidation process demonstrates a good and stable performance. The mathematical modeling of the methane partial oxidation process in the catalytic membrane reactor has been provided. The developed model was applied to find the process (temperature, gas flow rates, etc.) and membrane (pore diameter of porous layer, thickness of porous layer) parameters corresponding to highest methane conversion and syngas selectivity.

Shelepova E. , Vedyagin A. , Sadykov V. , Mezentseva N. , Fedorova Y. , Smorygo O. , Klenov O. , Mishakov I.
Theoretical and Experimental Study of Methane Partial Oxidation to Syngas in Catalytic Membrane Reactor with Asymmetric Oxygen-Permeable Membrane
Catalysis Today. 2016. V.268. P.103-110. DOI: 10.1016/j.cattod.2016.01.005 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 28, 2015
Accepted:	Jan 5, 2016
Published online:	Feb 3, 2016
Published print:	Jun 15, 2016

Web of science:	WOS:000375034900013
Scopus:	2-s2.0-85027921639
Elibrary:	26782174
Chemical Abstracts:	2016:139875
Chemical Abstracts (print):	164:451542
OpenAlex:	W2261467684

DB	Citing
Web of science	30
Scopus	34
Elibrary	32
OpenAlex	34