Solid Fuel Chemistry | Sciact - CRIS-system of Boreskov Institute of Catalysis

Solid Fuel Chemistry Full article

Journal

Polyhedron
ISSN: 0277-5387

Output data

Year: 2012, Volume: 31, Number: 1, Pages: 235-240 Pages count : 6 DOI: 10.1016/j.poly.2011.09.024

Tags

Copper(II), Polymerizations, Pyrazolylpyrimidines, Stacking, Supramolecular structure, Synthesis

Authors

Bushuev Mark B. ^1,2 , Krivopalov Viktor P. ³ , Lider Elizaveta V. ^1,2 , Semikolenova Nina V. ⁴ , Pervukhina N.V. ¹ , Naumov Dmitrii Yu. ¹ , Lavrenova Ludmila G. ^1,2 , Zakharov Vladimir A. ⁴ , Larionov Stanislav V. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Akad. Lavrentiev Ave., Novosibirsk 630090, Russia
2	Novosibirsk State University, 2, Pirogova Str., Novosibirsk 630090, Russia
3	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9, Akad. Lavrentiev Ave., Novosibirsk 630090, Russia
4	Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, 5, Akad. Lavrentiev Ave., Novosibirsk 630090, Russia

The copper(II) complexes CuLCl2 (1) and CuLBr2 (2), with the chelating pyrazolylpyrimidine ligand 4-(3,5-dimethyl-1H-pyrazol-1-yl)-2-methyl-6-phenylpyrimidine (L), have been synthesized. A single crystal X-ray diffraction study revealed that 1 and 2 have molecular mononuclear structures. The molecules of 1 and 2 form chains in the crystal structures of these compounds due to the formation of π–π-stacking interactions between the pyrimidine and the phenyl rings. The complexes, in combination with the co-catalyst methylaluminoxane (MAO), reveal catalytic activity in ethylene polymerization, while the free ligand L is inactive.

Bushuev M.B. , Krivopalov V.P. , Lider E.V. , Semikolenova N.V. , Pervukhina N.V. , Naumov D.Y. , Lavrenova L.G. , Zakharov V.A. , Larionov S.V.
Solid Fuel Chemistry
Polyhedron. 2012. V.31. N1. P.235-240. DOI: 10.1016/j.poly.2011.09.024 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 6, 2011
Accepted:	Sep 13, 2011
Published online:	Oct 7, 2011
Published print:	Jan 1, 2012

Web of science:	WOS:000300642900031
Scopus:	2-s2.0-84155166806
Elibrary:	17970669
Chemical Abstracts:	2011:1643079
Chemical Abstracts (print):	156:113280
OpenAlex:	W2093960198

DB	Citing
Web of science	3
Scopus	5
Elibrary	4
OpenAlex	5