MeOx/Al2O3 and MeOx/CeO2 (Me = Fe, Co, Ni) Catalysts for High Temperature N2O Decomposition and NH3 Oxidation Научная публикация
Журнал |
Catalysis Science and Technology
ISSN: 2044-4753 , E-ISSN: 2044-4761 |
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Вых. Данные | Год: 2016, Том: 6, Номер: 7, Страницы: 2150-2161 Страниц : 12 DOI: 10.1039/C5CY01381J | ||||
Ключевые слова | Alumina; Catalyst activity; Cobalt compounds; Dispersions; Nickel | ||||
Авторы |
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Организации |
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Реферат:
A series of MeOx/Al2O3 and MeOx/CeO2 (Me = Fe, Co, Ni) compounds was prepared by incipient wetness impregnation and characterized by XRD, XPS, UV-vis DRS, differential dissolution phase analysis (DDPA). Their activity towards N2O decomposition and ammonia oxidation at 750–900 °C was shown to depend on oxygen mobility in the sample as characterized by steady state isotopic transient kinetic analysis (18O SSITKA) and dispersion of MeOx (Me = Fe) species. Obvious reverse “activity-FeOx dispersion” dependence was related to the change of contribution from oxygen transfer from the support to active sites through the Me–ceria or not improbably, the Me–alumina interface. It was shown that the high efficiency of CeO2 based samples in deN2O can be additionally increased by CeO2 supporting onto high surface area alumina
Библиографическая ссылка:
Pinaeva L.G.
, Prosvirin I.P.
, Dovlitova L.S.
, Danilova I.G.
, Sadovskaya E.M.
, Isupova L.A.
MeOx/Al2O3 and MeOx/CeO2 (Me = Fe, Co, Ni) Catalysts for High Temperature N2O Decomposition and NH3 Oxidation
Catalysis Science and Technology. 2016. V.6. N7. P.2150-2161. DOI: 10.1039/C5CY01381J WOS Scopus РИНЦ CAPlusCA OpenAlex
MeOx/Al2O3 and MeOx/CeO2 (Me = Fe, Co, Ni) Catalysts for High Temperature N2O Decomposition and NH3 Oxidation
Catalysis Science and Technology. 2016. V.6. N7. P.2150-2161. DOI: 10.1039/C5CY01381J WOS Scopus РИНЦ CAPlusCA OpenAlex
Файлы:
Полный текст от издателя
Даты:
Поступила в редакцию: | 21 авг. 2015 г. |
Принята к публикации: | 24 окт. 2015 г. |
Опубликована online: | 30 окт. 2015 г. |
Опубликована в печати: | 7 апр. 2016 г. |
Идентификаторы БД:
Web of science: | WOS:000373608400016 |
Scopus: | 2-s2.0-84963722044 |
РИНЦ: | 26790255 |
Chemical Abstracts: | 2015:1745869 |
Chemical Abstracts (print): | 164:409320 |
OpenAlex: | W1868355315 |