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Study of the Composition and Morphology of New Modifications of Titanium-Magnesium Catalysts with Improved Properties in Ethylene Polymerization Full article

Journal Journal of Polymer Science, Part A: Polymer Chemistry
ISSN: 0887-624X , E-ISSN: 1099-0518
Output data Year: 2016, Volume: 54, Number: 16, Pages: 2545-2558 Pages count : 14 DOI: 10.1002/pola.28132
Tags crystal structures, polyethylene (PE), pore structure, structure-property relations, Ziegler-Natta polymerization
Authors Mikenas Tatiana B. 1 , Koshevoy Evgeny I. 1 , Cherepanova Svetlana V. 1,2 , Zakharov Vladimir A. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Prospect Akademika Lavrentieva, 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, St. Pirogova 2, Novosibirsk 630090, Russia

Funding (1)

1 The Ministry of Education and Science of the Russian Federation 14.607.21.0046 (RFMEFI60714X0046)

Abstract: Data on new modifications of supported titanium-magnesium catalysts (TMCs) with improved performance in ethylene polymerization are reported. These catalysts possess a high and stable activity, an enhanced ability to regulate molecular weight of the polymer by hydrogen, a controllable particle size at a narrow particle size distribution, and the ability to produce the polymer with an increased bulk density. Various physicochemical methods were used to obtain data on the chemical composition of novel supports and catalysts, their phase composition and crystal structure as well as the pore structure. The results obtained were used to discuss possible correlations between composition and structure of TMCs and their catalytic properties
Cite: Mikenas T.B. , Koshevoy E.I. , Cherepanova S.V. , Zakharov V.A.
Study of the Composition and Morphology of New Modifications of Titanium-Magnesium Catalysts with Improved Properties in Ethylene Polymerization
Journal of Polymer Science, Part A: Polymer Chemistry. 2016. V.54. N16. P.2545-2558. DOI: 10.1002/pola.28132 WOS Scopus РИНЦ РИНЦ ANCAN OpenAlex
Dates:
Submitted: Dec 21, 2015
Accepted: Mar 29, 2016
Published online: Apr 26, 2016
Published print: Aug 15, 2016
Identifiers:
Web of science: WOS:000383674100011
Scopus: 2-s2.0-84992306065
Elibrary: 27151116 | 41770495
Chemical Abstracts: 2016:667840
Chemical Abstracts (print): 165:91787
OpenAlex: W2344258466
Citing:
DB Citing
Web of science 23
Scopus 24
Elibrary 7 22
OpenAlex 24
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