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Hydrogen Production by Autothermal Reforming of Methane over Lanthanum Chromites Modified with Ru and Sr Научная публикация

Конференция XI HYdrogen POwer THeoretical and Engineering Solutions International Symposium
06-09 сент. 2015 , Toledo
Журнал International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487
Вых. Данные Год: 2016, Том: 41, Номер: 42, Страницы: 19373-19381 Страниц : 9 DOI: 10.1016/j.ijhydene.2016.05.029
Ключевые слова Autothermal reforming, Chromite, Lanthanum, Perovskite, Ruthenium, Strontium
Авторы Mota N. 1 , Ismagilov I.Z. 2 , Matus E.V. 2 , Kuznetsov V.V. 2 , Kerzhentsev M.A. 2 , Ismagilov Z.R. 2,3 , Navarro R.M. 1 , Fierro G.J. 1
Организации
1 Instituto de Catalisis y Petroleoquı´mica (CSIC), Sustainable Energy and Chemistry Group (EQS), Marie Curie 2, 28049 Madrid, Spain
2 Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
3 Institute of Coal Chemistry and Material Science SB RAS, Pr. Sovetskiy 18, Kemerovo 650000, Russia

Информация о финансировании (2)

1 European Commission 262840 FP7-NMP-2010-LARGE-4 DEMCAMER
2 European Union
Comunidad de Madrid 		S2013/MAE-2882

Реферат: The partial substitution of La by Sr in lanthanum chromites (La1−ySryCr0.85Ru0.15O3, y = 0.01, 0.02, 0.05) produced changes in the size, insertion degree of Ru and oxygen vacancies of the perovskite structure. The surface and structural modifications of the La1−ySryCr0.85Ru0.15O3 perovskites brought about by substitution of La by Sr directly affected the catalytic behaviour of the perovskites in the autothermal reforming of methane (ATR). It was found that all La1−ySryCr0.85Ru0.15O3 perovskites showed excellent ATR activity that it increased with the Sr substitution degree in the perovskite. The most active Sr-substituted chromite also showed high stability and thiotolerance in the long ATR durability test in the presence of 50 ppm of sulphur. Characterization of used samples revealed not only good structural stability of the Sr-substituted perovskites under the ATR conditions but also absence of carbon deposition on the surface of used catalyst in the ATR reaction.
Библиографическая ссылка: Mota N. , Ismagilov I.Z. , Matus E.V. , Kuznetsov V.V. , Kerzhentsev M.A. , Ismagilov Z.R. , Navarro R.M. , Fierro G.J.
Hydrogen Production by Autothermal Reforming of Methane over Lanthanum Chromites Modified with Ru and Sr
International Journal of Hydrogen Energy. 2016. V.41. N42. P.19373-19381. DOI: 10.1016/j.ijhydene.2016.05.029 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 3 мар. 2016 г.
Принята к публикации: 6 мая 2016 г.
Опубликована online: 25 мая 2016 г.
Опубликована в печати: 9 нояб. 2016 г.
Идентификаторы БД:
Web of science: WOS:000386741800041
Scopus: 2-s2.0-84969651793
РИНЦ: 27156572
Chemical Abstracts: 2016:842875
Chemical Abstracts (print): 165:465684
OpenAlex: W2405127129
Цитирование в БД:
БД Цитирований
Web of science 25
Scopus 26
РИНЦ 27
OpenAlex 28
Альметрики: