Thermolysis Characteristics of Salts of o-Phthalic Acid with the Formation of Fe, Co, Ni, Cu Metal Particles | Sciact - CRIS-system of Boreskov Institute of Catalysis

Thermolysis Characteristics of Salts of o-Phthalic Acid with the Formation of Fe, Co, Ni, Cu Metal Particles Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2016, Volume: 90, Number: 6, Pages: 1206-1211 Pages count : 6 DOI: 10.1134/S0036024416060315

Tags

composites, nanoparticles, phthalates, thermolysis, transition metals

Authors

Yudanova L.I. ¹ , Logvinenko V.A. ^1,3 , Yudanov N.F. ¹ , Rudina N.A. ² , Ishchenko A.V. ^2,3 , Korolʹkov I.V. ^1,3 , Semyannikov P.P. ¹ , Sheludyakova L.A. ^1,3 , Alferova N.I. ¹

Affiliations

1	Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
3	Novosibirsk State University, Novosibirsk, 630090 Russia

Studies of the thermolysis of ortho-[Ni(H2O)2(C8H4O4)](H2O)2, [Cu(H2O)(C8H4O4)], and acid [M(H2O)6](C8H5O4)2 (M(II) = Fe(II), Co(II), and Ni(II)), [Cu(H2O)2(C8H5O4)2] phthalates reveal that the solid products of their decomposition are composites with nanoparticles embedded in carbon–polymer matrices. Metallic nanoparticles with oxide nanoparticle impurities are detected in iron/cobalt polymer composites, while nickel/copper composites are composed of only metallic particles. It is found that nickel nanoparticles with the diameters of 6–8 nm are covered with disordered graphene layers, while the copperbased composite matrix contains spherical conglomerates (50–200 nm) with numerous spherical Cu particles (5–10 nm).

Yudanova L.I. , Logvinenko V.A. , Yudanov N.F. , Rudina N.A. , Ishchenko A.V. , Korolʹkov I.V. , Semyannikov P.P. , Sheludyakova L.A. , Alferova N.I.
Thermolysis Characteristics of Salts of o-Phthalic Acid with the Formation of Fe, Co, Ni, Cu Metal Particles
Russian Journal of Physical Chemistry A. 2016. V.90. N6. P.1206-1211. DOI: 10.1134/S0036024416060315 WOS Scopus РИНЦ AN OpenAlex

Юданова Л.И. , Логвиненко В.А. , Юданов Н.Ф. , Рудина Н.А. , Ищенко А.В. , Корольков И.В. , Семянников П.П. , Шелудякова Л.А. , Алферова Н.И.
Характеристики термолиза солей орто-фталевой кислоты с образованием наночастиц металлов (Fe(II), Co(II), Ni(II), Cu(II))
Журнал физической химии. 2016. Т.90. №6. С.896-901. DOI: 10.7868/S0044453716060315 РИНЦ OpenAlex

Submitted:	Jun 26, 2015
Published online:	May 21, 2016
Published print:	Jun 1, 2016

Web of science:	WOS:000376605500017
Scopus:	2-s2.0-84971635750
Elibrary:	27097219
Chemical Abstracts:	2016:865478
OpenAlex:	W2406061756

DB	Citing
Web of science	4
Scopus	4
Elibrary	5
OpenAlex	5