Sciact
  • EN
  • RU

Liquid Phase Oxidation of Alkenes with Nitrous Oxide to Carbonyl Compounds Full article

Journal Advanced Synthesis and Catalysis
ISSN: 1615-4150 , E-ISSN: 1615-4169
Output data Year: 2004, Volume: 346, Number: 2-3, Pages: 268-274 Pages count : 7 DOI: 10.1002/adsc.200303155, 10.1002/chin.200431044
Tags Alkenes oxidation, Carbene, Carbonyl compounds, Cycloheptatriene, Cyclopropane, Methylene, Nitrous oxide
Authors Starokon E.V. 1 , Dubkov K.A. 1 , Babushkin D.E. 1 , Parmon V.N. 1 , Panov G.I. 1
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russia

Funding (1)

1 Президиум РАН 9.3

Abstract: A variety of substrates including linear, cyclic, heterocyclic alkenes and their derivatives were tested in the liquid phase non-catalytic oxidation with nitrous oxide (N2O). The structure and composition of the alkenes have a significant effect on the reaction selectivity. With many alkenes, N2O oxidation provides a selective way for the preparation of carbonyl compounds. The generation of carbene (or diazomethane) species is a remarkable feature of the oxidation of terminal alkenes.
Cite: Starokon E.V. , Dubkov K.A. , Babushkin D.E. , Parmon V.N. , Panov G.I.
Liquid Phase Oxidation of Alkenes with Nitrous Oxide to Carbonyl Compounds
Advanced Synthesis and Catalysis. 2004. V.346. N2-3. P.268-274. DOI: 10.1002/adsc.200303155, 10.1002/chin.200431044 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Oct 1, 2003
Accepted: Jan 12, 2004
Published print: Feb 1, 2004
Published online: Mar 29, 2004
Identifiers:
Web of science: WOS:000220763400021
Scopus: 2-s2.0-1942503289
Elibrary: 13450411
Chemical Abstracts: 2004:323446
Chemical Abstracts (print): 141:295423
OpenAlex: W2949294496
Citing:
DB Citing
Web of science 48
Scopus 52
Elibrary 55
OpenAlex 52
Altmetrics: