Реферат: Adsorption of H2PdCl4 from aqueous solutions on the surface of graphite-like carbon materials proceeds through two competitive pathways: reduction, which gives rise to Pd ° particles of 6–100nm in size, and formation of π-complexes of PdCl2 with >CC< fragments of the carbon matrix: Process (1) is localized near the exterior surface of the porous carbon particles. Process (2) takes place on the whole surface of these particles. The quantitative ratio of the adsorbed palladium species (Pd2+ and Pd °) and also the dispersion and morphology of the metallic particles depend on the mode of contact of the H2PdCl4 solution with the carbon, the composition of the gas phase, the size of the carbon particles, the chemical state of the carbon surface and the conditions of drying. The results obtained are explained in terms of the electrochemical theory of carbon reactivity.

Библиографическая ссылка: Simonov P.A. , Romanenko A.V. , Prosvirin I.P. , Moroz E.M. , Boronin A.I. , Chuvilin A.L. , Likholobov V.A.
On the Nature of the Interaction of H2PdCl4 with the Surface of Graphite-Like Carbon Materials
Carbon. 1997. V.35. N1. P.73-82. DOI: 10.1016/S0008-6223(96)00129-7 WOS Scopus РИНЦ CAPlusCA OpenAlex

Даты:

Поступила в редакцию:	4 апр. 1996 г.
Принята к публикации:	15 июл. 1996 г.
Опубликована в печати:	1 янв. 1997 г.
Опубликована online:	19 мая 1998 г.

Идентификаторы БД:

Web of science:	WOS:A1997WF68900010
Scopus:	2-s2.0-0002993202
РИНЦ:	13250458
Chemical Abstracts:	1997:114511
Chemical Abstracts (print):	126:180420
OpenAlex:	W2020353000

Цитирование в БД:

БД	Цитирований
Web of science	82
Scopus	87
РИНЦ	90
OpenAlex	85

Альметрики: