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Catalytic Filamentous Carbon: Structural and Textural Properties Научная публикация

Журнал Carbon
ISSN: 0008-6223 , E-ISSN: 1873-3891
Вых. Данные Год: 2003, Том: 41, Номер: 8, Страницы: 1605-1615 Страниц : 11 DOI: 10.1016/S0008-6223(03)00115-5
Ключевые слова A. Carbon filaments, B. Chemical vapor deposition, C. Raman spectroscopy, Transmission electron microscopy, D. Texture
Авторы Reshetenko T.V. 1 , Avdeeva L.B. 1 , Ismagilov Z.R. 1 , Pushkarev V.V. 2 , Cherepanova S.V. 1 , Chuvilin A.L. 1 , Likholobov V.A. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akad. Lavrentieva 5, Novosibirsk 630090, Russia
2 Department of Chemical and Petroleum Engineering, University of Pittsburgh, 1249 Benedum Hall, Pittsburgh, PA 15260, USA

Информация о финансировании (2)

1 Civilian Research and Development Foundation REC-008
2 Netherlands Organisation for Scientific Research

Реферат: Catalytic filamentous carbon (CFC) synthesized by the decomposition of methane over iron subgroup metal catalysts (Ni, Co, Fe or their alloys) is a new family of mesoporous carbon materials possessing the unique structural and textural properties. Microstructural properties of CFC (arrangement of the graphite planes in filaments) are shown to depend on the nature of catalyst for methane decomposition. These properties widely vary for different catalysts: the angle between graphite planes and the filament axis can be 0° (Fe–Co–Al2O3), 15° (Co–Al2O3), 45° (Ni–Al2O3), 90° (Ni–Cu–Al2O3). The textural properties of CFC depend both on the catalyst nature and the conditions of methane decomposition (T, °C). The micropore volume in CFC is very low, 0.001–0.022 cm3 g−1 at the total pore volume of 0.26–0.59 cm3 g−1. Nevertheless, the BET surface area may reach 318 m2 g−1. Results of the TEM (HRTEM), XRD, Raman spectroscopic, SEM and adsorption studies of the structural and textural properties of CFC are discussed.
Библиографическая ссылка: Reshetenko T.V. , Avdeeva L.B. , Ismagilov Z.R. , Pushkarev V.V. , Cherepanova S.V. , Chuvilin A.L. , Likholobov V.A.
Catalytic Filamentous Carbon: Structural and Textural Properties
Carbon. 2003. V.41. N8. P.1605-1615. DOI: 10.1016/S0008-6223(03)00115-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована в печати: 1 янв. 2003 г.
Поступила в редакцию: 25 янв. 2003 г.
Принята к публикации: 3 мар. 2003 г.
Опубликована online: 30 мая 2003 г.
Идентификаторы БД:
Web of science: WOS:000183674700016
Scopus: 2-s2.0-0037603132
РИНЦ: 13426927
Chemical Abstracts: 2003:425070
Chemical Abstracts (print): 139:186426
OpenAlex: W1985247491
Цитирование в БД:
БД Цитирований
Web of science 139
Scopus 148
РИНЦ 159
OpenAlex 136
Альметрики: