Kinetics of Rapeseed Oil Transesterification over a Heterogeneous Barium–Aluminum Oxide Catalyst with the Methanol Pressure Taken into Account | Sciact - CRIS-система Института катализа

Kinetics of Rapeseed Oil Transesterification over a Heterogeneous Barium–Aluminum Oxide Catalyst with the Methanol Pressure Taken into Account Научная публикация

Журнал

Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555

Вых. Данные

Год: 2013, Том: 5, Номер: 4, Страницы: 342-349 Страниц : 8 DOI: 10.1134/S2070050413040090

Ключевые слова

biodiesel, heterogeneous catalyst, kinetics, methanol pressure, rapeseed oil, transesterification

Авторы

Zavarukhin S.G. ¹ , Ivanova A.S. ¹ , Kukushkin R.G. ² , Lebedev M.Yu. ¹ , Simonov A.N. ¹ , Sherstyuk O.V. ¹ , Yakovlev V.A. ¹ , Trusov L.I. ³

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Novosibirsk State University, Novosibirsk, 630090 Russia
3	OOOASPEKT, Moscow, 119571 Russia

Информация о финансировании (1)

Министерство образования и науки Российской Федерации

16.526.11.6003

Use of heterogeneous catalysts in the synthesis of biodiesel from vegetable lipids via transesterification with alcohols has certain advantages over use of homogeneous catalysts. Commercialization of this process needs investigation of its kinetics. Here, we report, for the first time, the kinetics of transesterification of rapeseed oil with gaseous methanol over a heterogeneous catalyst with methanol partial pressure taken into account. Experiments have been carried out in a flow reactor with a fixed bed of a barium-aluminum oxide catalyst at 200°C and a methanol pressure of 0.1–2.5 MPa. Experimental data have been processed in terms of a simplified kinetic model involving one irreversible second-order reaction (first-order reaction with respect to both oil and methanol). Service life tests have been carried out for the catalyst calcined at 700°C.

Zavarukhin S.G. , Ivanova A.S. , Kukushkin R.G. , Lebedev M.Y. , Simonov A.N. , Sherstyuk O.V. , Yakovlev V.A. , Trusov L.I.
Kinetics of Rapeseed Oil Transesterification over a Heterogeneous Barium–Aluminum Oxide Catalyst with the Methanol Pressure Taken into Account
Catalysis in Industry. 2013. V.5. N4. P.342-349. DOI: 10.1134/S2070050413040090 WOS Scopus РИНЦ OpenAlex

Заварухин С.Г. , Иванова А.С. , Кукушкин Р.Г. , Лебедев М.Ю. , Симонов А.Н. , Шерстюк О.В. , Яковлев В.А. , Трусов Л.И.
Кинетика переэтерификации рапсового масла на гетерогенном барий-алюмооксидном катализаторе с учетом давления метанола
Катализ в промышленности. 2013. №3. С.67-74. РИНЦ CAPlusCA

Поступила в редакцию:	6 мар. 2013 г.
Опубликована в печати:	1 окт. 2013 г.
Опубликована online:	17 дек. 2013 г.

Web of science:	WOS:000433667800008
Scopus:	2-s2.0-84891811577
РИНЦ:	21906361
OpenAlex:	W2024428586

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